Selective oxidation of glycerol to lactic acid over activated carbon supported Pt catalyst in alkaline solution
文献类型：期刊论文
| 作者 | Wang, Tao1; Ding, Yunjie1,2; Zhang, Chen1,3; Liu, Xiao1,3 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2016-04-01 |
| 卷号 | 37期号:4页码:502-509 |
| 关键词 | Glycerol Lactic Acid Platinum Activated Carbon Oxidation Base Type |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(15)61055-5 |
| 文献子类 | Article |
| 英文摘要 | Pt/activated carbon (Pt/AC) catalyst combined with base works efficiently for lactic acid production from glycerol under mild conditions. Base type (LiOH, NaOH, KOH, or Ba(OH)(2)) and base/glycerol molar ratio significantly affected the catalytic performance. The corresponding lactic acid selectivity was in the order of LiOH > NaOH > KOH > Ba(OH)(2). An increase in LiOH/glycerol molar ratio ewlevated the glycerol conversion and lactic acid selectivity to some degree, but excess LiOH inhibited the transformation of glycerol to lactic acid. In the presence of Pt/AC catalyst, the maximum selectivity of lactic acid was 69.3% at a glycerol conversion of 100% after 6 h at 90 degrees C, with a LiOH/glycerol molar ratio of 1.5. The Pt/AC catalyst was recycled five times and was found to exhibit slightly decreased glycerol conversion and stable lactic acid selectivity. In addition, the experimental results indicated that reaction intermediate dihydroxyacetone was more favorable as the starting reagent for lactic acid formation than glyceraldehyde. However, the Pt/AC catalyst had adverse effects on the intermediate transformation to lactic acid, because it favored the catalytic oxidation of them to glyceric acid. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | FREE AQUEOUS-SOLUTION ; HYDROTHERMAL REACTION ; CONVERSION ; OXYGEN ; BASE ; WATER ; DIHYDROXYACETONE ; HYDROGENOLYSIS ; NANOPARTICLES ; PERSPECTIVES |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000374082700006 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170754]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Tao; Ding, Yunjie |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Tao,Ding, Yunjie,Zhang, Chen,et al. Selective oxidation of glycerol to lactic acid over activated carbon supported Pt catalyst in alkaline solution[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(4):502-509. |
| APA | Wang, Tao,Ding, Yunjie,Zhang, Chen,&Liu, Xiao.(2016).Selective oxidation of glycerol to lactic acid over activated carbon supported Pt catalyst in alkaline solution.CHINESE JOURNAL OF CATALYSIS,37(4),502-509. |
| MLA | Wang, Tao,et al."Selective oxidation of glycerol to lactic acid over activated carbon supported Pt catalyst in alkaline solution".CHINESE JOURNAL OF CATALYSIS 37.4(2016):502-509. |
入库方式： OAI收割
来源：大连化学物理研究所
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