Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions
文献类型：期刊论文
| 作者 | Hu, Shu-Bo; Zhou, Ji; Zhou, Yong-Gui; Chen, Zhang-Pei |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2016-04-27 |
| 卷号 | 57期号:17页码:1925-1929 |
| 关键词 | Fluorinated Diphosphine Ligand Rhodium 1 4-addition Reactions |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2016.03.072 |
| 文献子类 | Article |
| 英文摘要 | A novel electronically deficient chiral diphosphine ligand (R-ax,S,S)-F-12-C-3-TunePhos has been concisely synthesized. The electron-poor ligand features both chiral centers and chiral axis bearing fluoro-functional groups on each phosphorus phenyl ring based on C-3-TunePhos backbone. The catalyst composed of this ligand and rhodium showed excellent activities and enantioselectivities in asymmetric 1,4-addition reactions of arylboronic acids to diverse alpha,beta-unsaturated ketones with up to 99% ee. (C) 2016 Elsevier Ltd. All rights reserved. |
| WOS关键词 | CHIRAL DIPHOSPHINE LIGANDS ; CATALYZED STEREOSELECTIVE REACTIONS ; ENANTIOSELECTIVE HYDROGENATION ; ARYLBORONIC ACIDS ; ORGANOBORONIC ACIDS ; CONJUGATE ADDITION ; OLEFIN LIGANDS ; ALPHA,BETA-UNSATURATED KETONES ; PHOSPHORUS LIGANDS ; MEOBIPHEP ANALOGS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000374601000025 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170774]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhou, Yong-Gui |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Shu-Bo,Zhou, Ji,Zhou, Yong-Gui,et al. Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions[J]. TETRAHEDRON LETTERS,2016,57(17):1925-1929. |
| APA | Hu, Shu-Bo,Zhou, Ji,Zhou, Yong-Gui,&Chen, Zhang-Pei.(2016).Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions.TETRAHEDRON LETTERS,57(17),1925-1929. |
| MLA | Hu, Shu-Bo,et al."Electronically deficient (R-ax,S,S)-F-12-C-3-TunePhos and its applications in asymmetric 1,4-addition reactions".TETRAHEDRON LETTERS 57.17(2016):1925-1929. |
入库方式： OAI收割
来源：大连化学物理研究所
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