Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions
文献类型：期刊论文
| 作者 | Qiu, Di; Zhang, Yan; Wang, Jianbo; Wang, Bo |
| 刊名 | BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2016-04-25 |
| 卷号 | 12页码:796-804 |
| 关键词 | Alkane Diazo Compounds C-h Bond Functionalization C-h Bond Insertion Metal-carbene Site-selectivity |
| ISSN号 | 1860-5397 |
| DOI | 10.3762/bjoc.12.78 |
| 文献子类 | Review |
| 英文摘要 | The recent development of intermolecular C-H insertion in the application of C(sp(3))-H bond functionalizations, especially for light alkanes, is reviewed. The challenging problem of regioselectivity in C-H bond insertions has been tackled by the use of sterically bulky metal catalysts, such as metal porphyrins and silver(I) complexes. In some cases, high regioselectivity and enantioselectivity have been achieved in the C-H bond insertion of small alkanes. This review highlights the most recent accomplishments in this field. |
| WOS关键词 | C-H BONDS ; CARBON-HYDROGEN BONDS ; CATALYTIC ENANTIOSELECTIVE SYNTHESIS ; ALKANES ; ACTIVATION ; METHANE ; COMPLEXES ; ETHERS ; CYCLOPROPANATION ; REARRANGEMENT |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000374650200001 |
| 出版者 | BEILSTEIN-INSTITUT |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170778]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiu, Di,Zhang, Yan,Wang, Jianbo,et al. Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions[J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,2016,12:796-804. |
| APA | Qiu, Di,Zhang, Yan,Wang, Jianbo,&Wang, Bo.(2016).Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions.BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,12,796-804. |
| MLA | Qiu, Di,et al."Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions".BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 12(2016):796-804. |
入库方式： OAI收割
来源：大连化学物理研究所
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