Cyclization of Pseudoionone Catalyzed by Sulfuric Acid in a Microreactor
文献类型：期刊论文
| 作者 | Zhou, Feng1,2; Zhang, Boyu1; Yao, Chaoqun1; Zhu, Kai1,2; Yang, Mei1; Chen, Guangwen1 |
| 刊名 | CHEMICAL ENGINEERING & TECHNOLOGY
 |
| 出版日期 | 2016-05-01 |
| 卷号 | 39期号:5页码:849-856 |
| 关键词 | Cyclization Ionone Microchannel Microreactor Pseudoionone |
| ISSN号 | 0930-7516 |
| DOI | 10.1002/ceat.201500670 |
| 文献子类 | Article |
| 英文摘要 | A microreactor system was developed to investigate the cyclization of pseudoionone (PI) catalyzed by sulfuric acid. The conversion of PI and selectivities of alpha-ionone and beta-ionone were explored under various conditions. The effects of residence time, molar ratio of acid/PI (M-ratio), reaction temperature, and sulfuric acid concentration on the reaction were evaluated. Sulfuric acid concentration was found to play a vital role in the reaction system, which could greatly influence the conversion and selectivities. A high yield of beta-ionone and total yield of alpha-ionone and beta-ionone were achieved under optimized conditions. The formation of by-products was determined in detail and the side reactions could be restrained by optimizing the reaction parameters. |
| WOS关键词 | 2-PHASE MASS-TRANSFER ; INTENSIFICATION ; MICROCHANNEL ; EFFICIENT ; KINETICS ; REACTOR ; IONONE |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000374768200006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170822]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Chen, Guangwen |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Feng,Zhang, Boyu,Yao, Chaoqun,et al. Cyclization of Pseudoionone Catalyzed by Sulfuric Acid in a Microreactor[J]. CHEMICAL ENGINEERING & TECHNOLOGY,2016,39(5):849-856. |
| APA | Zhou, Feng,Zhang, Boyu,Yao, Chaoqun,Zhu, Kai,Yang, Mei,&Chen, Guangwen.(2016).Cyclization of Pseudoionone Catalyzed by Sulfuric Acid in a Microreactor.CHEMICAL ENGINEERING & TECHNOLOGY,39(5),849-856. |
| MLA | Zhou, Feng,et al."Cyclization of Pseudoionone Catalyzed by Sulfuric Acid in a Microreactor".CHEMICAL ENGINEERING & TECHNOLOGY 39.5(2016):849-856. |
入库方式： OAI收割
来源：大连化学物理研究所
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