Relationship between activity and structure of carbon materials for Br-2/Br- in zinc bromine flow batteries
文献类型：期刊论文
| 作者 | Lai, Qinzhi1; Wang, Chenhui1,3; Li, Xianfeng1,2; Xi, Xiaoli1,3; Xu, Pengcheng1; Zhang, Huamin1,2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:46页码:40169-40174 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c6ra03712g |
| 文献子类 | Article |
| 英文摘要 | Zinc bromine flow battery (ZBFB) is one of the highly efficient and low cost energy storage devices. However, the low operating current density hinders its progress. Developing high activity cathode materials is an efficient way to reduce cell electrochemical polarization and improve the operating current density. Thus, it is essential to study the relationship between the activity and structure of carbon materials to optimize the performance of ZBFB. The pore parameters and phase structure of four commercialized carbon materials were investigated by an N-2 sorption isotherm experiment and X-ray diffraction (XRD), respectively. The electrochemical property of the four carbon materials was systematically studied by cyclic voltammetry (CV), linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS) and the kinetic parameters and diffusion coefficients were calculated. The results indicate that specific surface area, pore size distribution and electrical conductivity are the main factors affecting the electrochemical activity of carbon materials. The carbon material with high surface area, suitable pore size distribution and excellent electrical conductivity shows high activity to the Br-2/Br- redox couple in ZBFB. This study lays foundations for developing cathode materials of excellent activity for ZBFB, which can efficiently improve the power density, reduce the stack size of the ZBFB and boost its potential for commercial application. |
| WOS关键词 | ENERGY-STORAGE ; REDOX ; PERFORMANCE ; NANOTUBES ; ELECTROLYTE ; PROGRESS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000374974300076 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170834]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Lai, Qinzhi; Zhang, Huamin |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Zhongshan Rd 457, Dalian 116023, Peoples R China 2.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lai, Qinzhi,Wang, Chenhui,Li, Xianfeng,et al. Relationship between activity and structure of carbon materials for Br-2/Br- in zinc bromine flow batteries[J]. RSC ADVANCES,2016,6(46):40169-40174. |
| APA | Lai, Qinzhi,Wang, Chenhui,Li, Xianfeng,Xi, Xiaoli,Xu, Pengcheng,&Zhang, Huamin.(2016).Relationship between activity and structure of carbon materials for Br-2/Br- in zinc bromine flow batteries.RSC ADVANCES,6(46),40169-40174. |
| MLA | Lai, Qinzhi,et al."Relationship between activity and structure of carbon materials for Br-2/Br- in zinc bromine flow batteries".RSC ADVANCES 6.46(2016):40169-40174. |
入库方式： OAI收割
来源：大连化学物理研究所
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