Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst
文献类型：期刊论文
| 作者 | Xu, Shutao1; Lei, Nian2,3; Wang, Jia2,3; Zhao, Xiaochen2; Li, Lin2; Zhang, Leilei2; Miao, Shu2; Pan, Xiaoli2; Wang, Aiqin2; Zhang, Tao2 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2016-04-21 |
| 卷号 | 9期号:8页码:784-790 |
| ISSN号 | 1864-5631 |
| 关键词 | Glycerol Hydrogenolysis Supported Catalysts Tungsten Oxide 1 3-propanediol |
| DOI | 10.1002/cssc.201501506 |
| 文献子类 | Article |
| 英文摘要 | Single/pseudo-single atom Pt catalyst was prepared on mesoporous WOx. The large surface area and abundant oxygen vacancies of WOx improve the Pt dispersion and stabilize the Pt isolation. This newly prepared catalyst exhibited outstanding hydrogenolysis activity under 1 MPa H-2 pressure with a very high space-time yield towards 1,3-propanediol (3.78 g g(Pt)(-1) h(-1)) in Pt-W catalysts. The highly isolated Pt structure is thought to contribute to the excellent H-2 dissociation capacity over Pt/WOx. The high selectivity towards 1,3-propanediol is attributed to the heterolytic dissociation of H-2 at the interface of Pt and WOx (providing specific Bronsted acid sites and the concerted dehydration-hydrogenation reaction) and the bond formation between glycerol and WOx, which favors/stabilizes the formation of a secondary carbocation intermediate as well as triggers the redox cycle of the W species (W6+ reversible arrow QW(5+)). |
| WOS关键词 | SELECTIVE HYDROGENOLYSIS ; IRIDIUM CATALYST ; CHEMICALS ; NANOSTRUCTURES ; OXIDATION ; BEHAVIOR ; POLYOLS ; METALS ; FILMS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000375113800002 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170856]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Aiqin; Zhang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Shutao,Lei, Nian,Wang, Jia,et al. Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst[J]. CHEMSUSCHEM,2016,9(8):784-790. |
| APA | Xu, Shutao.,Lei, Nian.,Wang, Jia.,Zhao, Xiaochen.,Li, Lin.,...&Zhang, Tao.(2016).Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst.CHEMSUSCHEM,9(8),784-790. |
| MLA | Xu, Shutao,et al."Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst".CHEMSUSCHEM 9.8(2016):784-790. |
入库方式： OAI收割
来源：大连化学物理研究所
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