Photocatalytic chemistry of methanol on rutile TiO2(011)-(2 x 1)
文献类型：期刊论文
| 作者 | Wang, Zhiqiang2; Hao, Qunqing2; Mao, Xinchun1; Zhou, Chuanyao2; Dai, Dongxu2; Yang, Xueming2 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2016-04-21 |
| 卷号 | 18期号:15页码:10224-10231 |
| ISSN号 | 1463-9076 |
| DOI | 10.1039/c6cp00556j |
| 文献子类 | Article |
| 英文摘要 | Photocatalytic chemistry of methanol on the reconstructed rutile TiO2(011)-(2 x 1) surface upon 266 nm and 400 nm light excitation has been investigated quantitatively using the post-irradiation temperature-programmed desorption (TPD) method. Photochemical products such as formaldehyde, methyl formate and water, which result from the recombination of surface bridging hydroxyls through the abstraction of lattice oxygen atoms, have been identified under both 266 nm and 400 nm light irradiation. However, ethylene is detected only under 266 nm light irradiation. Through an analogy experiment, ethylene production is attributed to the photochemistry and the following thermochemistry of formaldehyde. The absence of the ethylene signal under 400 nm light is consistent with the significantly lower conversion at this wavelength compared with 266 nm. The photocatalytic reaction rate of methanol is also wavelength dependent. Possible reasons for the photon energy dependent phenomena have been discussed. This work not only provides a detailed characterization of the photochemistry of methanol on the rutile TiO2(011)-(2 x 1) surface, but also indicates the importance of photon energy in the photochemistry on TiO2 surfaces. |
| WOS关键词 | TIO2 THIN-FILMS ; TITANIUM-DIOXIDE ; SURFACE-STRUCTURE ; TIO2(110) SURFACE ; METHYL FORMATE ; PHOTON ENERGY ; ACTIVE-SITES ; FORMALDEHYDE ; HYDROGEN ; DISSOCIATION |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000374350600041 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170858]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhou, Chuanyao; Yang, Xueming |
| 作者单位 | 1.China Acad Engn Phys, Inst Mat, Ctr Interface Dynam Sustainabil, Chengdu 610200, Sichuan, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Zhiqiang,Hao, Qunqing,Mao, Xinchun,et al. Photocatalytic chemistry of methanol on rutile TiO2(011)-(2 x 1)[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2016,18(15):10224-10231. |
| APA | Wang, Zhiqiang,Hao, Qunqing,Mao, Xinchun,Zhou, Chuanyao,Dai, Dongxu,&Yang, Xueming.(2016).Photocatalytic chemistry of methanol on rutile TiO2(011)-(2 x 1).PHYSICAL CHEMISTRY CHEMICAL PHYSICS,18(15),10224-10231. |
| MLA | Wang, Zhiqiang,et al."Photocatalytic chemistry of methanol on rutile TiO2(011)-(2 x 1)".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 18.15(2016):10224-10231. |
入库方式： OAI收割
来源：大连化学物理研究所
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