High performance solid-phase extraction cleanup method coupled with gas chromatography-triple quadrupole mass spectrometry for analysis of polychlorinated naphthalenes and dioxin-like polychlorinated biphenyls in complex samples
文献类型：期刊论文
| 作者 | Li, Fang1,2; Jin, Jing1; Tan, Dongqin1,2; Xu, Jiazhi1,2; Dhanjai1; Ni, Yuwen1; Zhang, Haijun1; Chen, Jiping1 |
| 刊名 | JOURNAL OF CHROMATOGRAPHY A
 |
| 出版日期 | 2016-05-27 |
| 卷号 | 1448页码:1-8 |
| 关键词 | Cleanup Solid-phase Extraction Magnesium Oxide Polychlorinated Naphthalenes Dioxin-like Polychlorinated Biphenyls |
| ISSN号 | 0021-9673 |
| DOI | 10.1016/j.chroma.2016.04.037 |
| 文献子类 | Article |
| 英文摘要 | A solid-phase extraction (SPE) cleanup method was developed to purify the sample extracts for the analysis of polychlorinated naphthalenes (PCNs) and dioxin-like polychlorinated biphenyls (dl-PCBs). Monodisperse magnesium oxide (MgO) microspheres and basic alumina were used as SPE adsorbents. Important parameters of the SPE procedure were optimized, including the amount of basic alumina and the type and volume of the washing and elution solvents. The optimized SPE cleanup method exhibited excellent purification performance for the removal of organochlorinated compounds, lipid compounds, sulfur, and pigments. Additionally, it was found that the retention activities of congeners differed with the number and position of the chlorine substituents in PCNs. In this study, an analytical method based on a combination of accelerated solvent extraction (ASE) coupled with SPE cleanup and gas chromatography triple quadrupole mass spectrometry (GC-MS/MS) is proposed for the analysis of PCNs and dl-PCBs in complex samples (sediment, pine needle, and scallop samples). The analytical method demonstrates good linearity, acceptable recovery (63-148%) and precision (relative standard deviations less than 26%). The limits of detection (LODs) of PCN and dl-PCB congeners were in the range of 0.6-19.1 pg g(-1) and 0.4-8.6 pg g(-1), respectively. The PCNs and dl-PCBs levels in these samples ranged from 0.16 to 3.07 ng g(-1) dry weight (dw) and from undetectable to 0.07 ng g(-1) dw, respectively. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | POLYBROMINATED DIPHENYL ETHERS ; DIBENZO-P-DIOXINS ; PHOCA-VITULINA ; PCBS ; SEDIMENTS ; ORGANOCHLORINES ; MICROSPHERES ; PESTICIDES ; POLLUTANTS ; NANOTUBES |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000376211600001 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170928]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Chen, Jiping |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Fang,Jin, Jing,Tan, Dongqin,et al. High performance solid-phase extraction cleanup method coupled with gas chromatography-triple quadrupole mass spectrometry for analysis of polychlorinated naphthalenes and dioxin-like polychlorinated biphenyls in complex samples[J]. JOURNAL OF CHROMATOGRAPHY A,2016,1448:1-8. |
| APA | Li, Fang.,Jin, Jing.,Tan, Dongqin.,Xu, Jiazhi.,Dhanjai.,...&Chen, Jiping.(2016).High performance solid-phase extraction cleanup method coupled with gas chromatography-triple quadrupole mass spectrometry for analysis of polychlorinated naphthalenes and dioxin-like polychlorinated biphenyls in complex samples.JOURNAL OF CHROMATOGRAPHY A,1448,1-8. |
| MLA | Li, Fang,et al."High performance solid-phase extraction cleanup method coupled with gas chromatography-triple quadrupole mass spectrometry for analysis of polychlorinated naphthalenes and dioxin-like polychlorinated biphenyls in complex samples".JOURNAL OF CHROMATOGRAPHY A 1448(2016):1-8. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。