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CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3

文献类型：期刊论文

作者Shang, Jianpeng1; Guo, Xiaoguang2; Li, Zuopeng1; Deng, Youquan3
刊名GREEN CHEMISTRY
出版日期2016
卷号18期号:10页码:3082-3088
ISSN号1463-9262
DOI10.1039/c5gc02772a
文献子类Article
英文摘要This paper reports an effective route for the syntheses of hydroxy carbamates from the reaction of CO2, epoxides and amines catalyzed by a Au/Fe2O3 catalyst. Under the optimized reaction conditions, various hydroxy carbamates were successfully synthesized with 92-98% isolated yields. The catalyst could be reused for several runs without deactivation. A plausible reaction mechanism was proposed by which the hydroxy carbamate was formed through an ammonium carbamate intermediate and the catalyst mainly promoted further nucleophilic addition between the epoxide and ammonium carbamate.
WOS关键词CARBON-DIOXIDE ; AU NANOPARTICLES ; HYDROGENATION ; CATALYSTS ; OXIDATION ; METHANOL ; AMINE ; PHASE ; DERIVATIVES ; MONOXIDE
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000376082400022
出版者ROYAL SOC CHEMISTRY
源URL[http://cas-ir.dicp.ac.cn/handle/321008/170938]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Shang, Jianpeng
作者单位1.Shanxi Datong Univ, Dept Chem & Environm Engn, Datong 037009, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714		 Shang, Jianpeng,Guo, Xiaoguang,Li, Zuopeng,et al. CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3[J]. GREEN CHEMISTRY,2016,18(10):3082-3088.
APA Shang, Jianpeng,Guo, Xiaoguang,Li, Zuopeng,&Deng, Youquan.(2016).CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3.GREEN CHEMISTRY,18(10),3082-3088.
MLA Shang, Jianpeng,et al."CO2 activation and fixation: highly efficient syntheses of hydroxy carbamates over Au/Fe2O3".GREEN CHEMISTRY 18.10(2016):3082-3088.

入库方式： OAI收割

来源：大连化学物理研究所

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