A novel CAU-10-H MOF membrane for hydrogen separation under hydrothermal conditions
文献类型：期刊论文
| 作者 | Jin, Hua1,2; Wollbrink, Alexander3; Yao, Rui1,2; Li, Yanshuo1; Caro, Juergen3; Yang, Weishen1 |
| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2016-09-01 |
| 卷号 | 513页码:40-46 |
| ISSN号 | 0376-7388 |
| 关键词 | Metal-organic Frameworks Cau-10-h Membrane Gas Permeation H-2/co2 Separation H-2/h2o Separation |
| DOI | 10.1016/j.memsci.2016.04.017 |
| 文献子类 | Article |
| 英文摘要 | Hydrogen selective membranes with excellent hydrothermal stability are highly demanded in ethanol steam reforming. For this goal, a novel CAU-10-H MOF membrane has been prepared on alpha-Al2O3 disc for the first time by in situ solvothermal synthesis. The as-prepared CAU-10-H membrane shows high selectivity for H-2 with mixed gas separation factors of 10.5 and 74.7 for H-2/CO2 and H-2/CH4 binary mixtures, respectively, indicating the successful synthesis of CAU-10-H membrane with high-quality. The performance of the CAU-10-H membrane for hydrogen separation in the presence of steam was systematically investigated by variation of feed pressure (2-5 bar) and temperature (150-300 degrees C). The CAU-10-H membrane is selective for H-2, with separation factors of 11.1 and 5.67 for H-2 over CO2 and H2O, respectively. More importantly, the CAU-10-H membrane is still structure-preserving and hydrogen-selective after long-term test under hydrothermal conditions. These results demonstrate that the CAU-10-H membrane is an excellent candidate for hydrogen separation in steam reforming of ethanol in a membrane reactor. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; MFI ZEOLITE MEMBRANES ; HIGH-TEMPERATURES ; WATER-VAPOR ; ETHANOL ; SELECTIVITY ; STABILITY ; ADSORPTION ; SORPTION ; SILICA |
| WOS研究方向 | Engineering ; Polymer Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000376301400005 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170968]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Yanshuo; Yang, Weishen |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Leibniz Univ Hannover, Inst Phys Chem & Electrochem, Callinstr 3, D-30167 Hannover, Germany |
| 推荐引用方式 GB/T 7714 | Jin, Hua,Wollbrink, Alexander,Yao, Rui,et al. A novel CAU-10-H MOF membrane for hydrogen separation under hydrothermal conditions[J]. JOURNAL OF MEMBRANE SCIENCE,2016,513:40-46. |
| APA | Jin, Hua,Wollbrink, Alexander,Yao, Rui,Li, Yanshuo,Caro, Juergen,&Yang, Weishen.(2016).A novel CAU-10-H MOF membrane for hydrogen separation under hydrothermal conditions.JOURNAL OF MEMBRANE SCIENCE,513,40-46. |
| MLA | Jin, Hua,et al."A novel CAU-10-H MOF membrane for hydrogen separation under hydrothermal conditions".JOURNAL OF MEMBRANE SCIENCE 513(2016):40-46. |
入库方式： OAI收割
来源：大连化学物理研究所
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