Preparation of decarboxylic-functionalized weak cation exchanger and application for simultaneous separation of alkali, alkaline earth and transition metals
文献类型：期刊论文
| 作者 | Peng, Yahui1; Gan, Yihui1; He, Chengxia1; Yang, Bingcheng1; Guo, Zhimou2; Liang, Xinmiao1 |
| 刊名 | TALANTA
 |
| 出版日期 | 2016-06-01 |
| 卷号 | 153页码:79-82 |
| 关键词 | Click Chemistry Weak Cation Exchanger Mercaptosuccinic Acid Ion Chromatography Stationary Phase |
| ISSN号 | 0039-9140 |
| DOI | 10.1016/j.talanta.2016.03.008 |
| 文献子类 | Article |
| 英文摘要 | A novel weak cation exchanger (WCX) with dicarboxyl groups functionalized has been developed by clicking mercaptosuccinic acid onto silica gel. The simple synthesis starts with modification of silica gel with triethoxyvinylsilane, followed by efficient coupling vinyl-bonded silica with mercaptosuccinic acid via a "thiol-ene" click reaction. The obtained WCX demonstrated good separation and high selectivity towards common metals. Simultaneous separation of 10 alkali, alkaline earth and transition metals was achieved within 12 min. Ion exchange and complex mechanism dominates the separation process. Its utility was demonstrated for determination of metals in tap water. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | INTERACTION LIQUID-CHROMATOGRAPHY ; ION CHROMATOGRAPHY ; STATIONARY-PHASE ; CLICK CHEMISTRY ; SILICA-GEL ; DIVALENT-CATIONS ; ZIRCONIUM ; ALUMINUM ; COLUMN |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000376052900012 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170970]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yang, Bingcheng |
| 作者单位 | 1.E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Yahui,Gan, Yihui,He, Chengxia,et al. Preparation of decarboxylic-functionalized weak cation exchanger and application for simultaneous separation of alkali, alkaline earth and transition metals[J]. TALANTA,2016,153:79-82. |
| APA | Peng, Yahui,Gan, Yihui,He, Chengxia,Yang, Bingcheng,Guo, Zhimou,&Liang, Xinmiao.(2016).Preparation of decarboxylic-functionalized weak cation exchanger and application for simultaneous separation of alkali, alkaline earth and transition metals.TALANTA,153,79-82. |
| MLA | Peng, Yahui,et al."Preparation of decarboxylic-functionalized weak cation exchanger and application for simultaneous separation of alkali, alkaline earth and transition metals".TALANTA 153(2016):79-82. |
入库方式： OAI收割
来源：大连化学物理研究所
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