Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes
文献类型：期刊论文
| 作者 | Wei, Baosheng1; Li, Heng1; Zhang, Wen-Xiong1; Xi, Zhenfeng1,2 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2016-05-23 |
| 卷号 | 35期号:10页码:1458-1463 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/acs.organomet.6b00073 |
| 文献子类 | Article |
| 英文摘要 | The development of Ca-mediated reactions is of great importance and is in great demand in both organometallic and organic chemistry. In this paper, we report that calcium iodide efficiently promotes the transformation of various 1,4-dilithio-1,3-butadienes into indenes or perfluorodibenzopentalenes, via an intramolecular C-H or C-F bond cleavage, respectively. In the reaction process, the Ca-induced s-cis/trans configurational isomerization of 1,4-dilithio-1,3-butadienes is followed by the subsequent nucleophilic C-H or C-F bond activation. |
| WOS关键词 | ALKALI-METAL COMPOUNDS ; DI-LITHIO REAGENTS ; STRUCTURAL-CHARACTERIZATION ; FACILE SYNTHESIS ; ORGANOMETALLIC COMPOUNDS ; COMPLEXES ; CATALYSTS ; ROUTE ; METALLOCENES ; REACTIVITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000376548400020 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170978]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Wen-Xiong; Xi, Zhenfeng |
| 作者单位 | 1.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China 2.Chinese Acad Sci, SIOC, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Baosheng,Li, Heng,Zhang, Wen-Xiong,et al. Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes[J]. ORGANOMETALLICS,2016,35(10):1458-1463. |
| APA | Wei, Baosheng,Li, Heng,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2016).Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes.ORGANOMETALLICS,35(10),1458-1463. |
| MLA | Wei, Baosheng,et al."Calcium-Mediated C-H and C-F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes".ORGANOMETALLICS 35.10(2016):1458-1463. |
入库方式： OAI收割
来源：大连化学物理研究所
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