Transition-Metal Controlled Diastereodivergent Radical Cyclization/Azidation Cascade of 1,7-Enynes
文献类型：期刊论文
| 作者 | Zhao, Yingying; Hu, Yancheng; Wang, Haolong; Li, Xincheng; Wan, Boshun |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2016-05-20 |
| 卷号 | 81期号:10页码:4412-4420 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.6b00655 |
| 文献子类 | Article |
| 英文摘要 | A strategy for achieving diastereodivergent azidations of enynes has been developed, employing azide transfer from the M-N-3 complex to alkyl radicals. Following this concept, the diastereoselectivity has been switched by modulating the transition metals and the ligands. The Mn(III)-mediated radical cyclization/azidation cascade of 1,7-enynes afforded trans-fused pyrrolo [3,4-c] quinolinones, whereas the Cu(II)/bipyridine system gave cis-products. |
| WOS关键词 | C-H AZIDATION ; ALPHA-ALLYLATION ; CATALYZED CYCLIZATION ; DUAL CATALYSIS ; PROPARGYLAMIDES ; ALKENES ; ACCESS ; 3,4-DIHYDROQUINOLIN-2(1H)-ONES ; MIGRATION ; OXIDATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000376476400051 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170994]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xincheng; Wan, Boshun |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Yingying,Hu, Yancheng,Wang, Haolong,et al. Transition-Metal Controlled Diastereodivergent Radical Cyclization/Azidation Cascade of 1,7-Enynes[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(10):4412-4420. |
| APA | Zhao, Yingying,Hu, Yancheng,Wang, Haolong,Li, Xincheng,&Wan, Boshun.(2016).Transition-Metal Controlled Diastereodivergent Radical Cyclization/Azidation Cascade of 1,7-Enynes.JOURNAL OF ORGANIC CHEMISTRY,81(10),4412-4420. |
| MLA | Zhao, Yingying,et al."Transition-Metal Controlled Diastereodivergent Radical Cyclization/Azidation Cascade of 1,7-Enynes".JOURNAL OF ORGANIC CHEMISTRY 81.10(2016):4412-4420. |
入库方式： OAI收割
来源：大连化学物理研究所
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