Influence of the state of Zn species over Zn-ZSM-5/ZSM-11 on the coupling effects of cofeeding n-butane with methanol
文献类型：期刊论文
| 作者 | Song, Chao2,3; Li, Xiujie2; Zhu, Xiangxue2; Liu, Shenglin2; Chen, Fucun2; Liu, Feng1; Xu, Longya2 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2016-06-05 |
| 卷号 | 519页码:48-55 |
| 关键词 | Zn State Cofeeding Methanol N-butane Aromatization |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2016.03.023 |
| 文献子类 | Article |
| 英文摘要 | Combination of the exothermic methanol aromatization with the endothermic n-butane aromatization provides a good way to meet the increasing demand for aromatics. Here, a series of Zn-ZSM-5/ZSM-11 catalysts were prepared with different introduction methods. The influence of location and state of Zn species on the coupling effects of cofeeding n-butane with methanol were investigated in detail. UV-vis, H-2-TPR and XPS spectra were applied to reveal the state of the Zn species on different catalysts. Quantitative results of NH3-TPD and Pyridine-FTIR were provided to compare the acidity changes of the catalyst after Zn loading. Physical mixing method led to high portion of bulk ZnO particles outside the channel which could promote the formation of C-2-C-4 light alkane in cofeeding reaction. Ion exchange and impregnation modes were beneficial for the formation of Zn-O-Zn bridging species in the micropore channel. Zn-O-Zn bridging species was found to increase the promoting effect of cofeeding n-butane with methanol on aromatics selectivity. (C) 2016 Published by Elsevier B.V. |
| WOS关键词 | RAY PHOTOELECTRON-SPECTROSCOPY ; LOADED ZSM-5/ZSM-11 ZEOLITE ; PROMOTED H-ZSM-5 CATALYSTS ; BRONSTED ACID SITES ; ZSM-5 ZEOLITES ; IN-SITU ; PROPANE AROMATIZATION ; ZN/MFI CATALYST ; LIGHT ALKANES ; ACTIVE-SITES |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000376700400006 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170998]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xiujie; Xu, Longya |
| 作者单位 | 1.Shanxi Yanchang Petr Grp Co Ltd, Yanan Refinery Plant, Luochuan 727406, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.SINOPEC, Beijing Res Inst Chem Ind, Beijing 100013, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Chao,Li, Xiujie,Zhu, Xiangxue,et al. Influence of the state of Zn species over Zn-ZSM-5/ZSM-11 on the coupling effects of cofeeding n-butane with methanol[J]. APPLIED CATALYSIS A-GENERAL,2016,519:48-55. |
| APA | Song, Chao.,Li, Xiujie.,Zhu, Xiangxue.,Liu, Shenglin.,Chen, Fucun.,...&Xu, Longya.(2016).Influence of the state of Zn species over Zn-ZSM-5/ZSM-11 on the coupling effects of cofeeding n-butane with methanol.APPLIED CATALYSIS A-GENERAL,519,48-55. |
| MLA | Song, Chao,et al."Influence of the state of Zn species over Zn-ZSM-5/ZSM-11 on the coupling effects of cofeeding n-butane with methanol".APPLIED CATALYSIS A-GENERAL 519(2016):48-55. |
入库方式： OAI收割
来源：大连化学物理研究所
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