中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hydrazine drastically promoted Fenton oxidation of bisphenol A catalysed by a Fe-III-Co Prussian blue analogue

文献类型:期刊论文

作者Li, Xuning1,2; Rykov, Alexandre I.1; Wang, Junhu1
刊名CATALYSIS COMMUNICATIONS
出版日期2016-03-05
卷号77页码:32-36
关键词Reducing Agent Fenton Mechanism Hz Coordinated Iron Site Mossbauer Spectroscopy
ISSN号1566-7367
DOI10.1016/j.catcom.2016.01.004
文献子类Article
英文摘要Herein, for the first time it has been demonstrated that hydrazine (Hz) could significantly promote the bisphenol A (BPA) degradation in the Fenton reaction catalysed by Fe[Co(CN)(6)]center dot 2H(2)O Prussian blue analogue (Fe-III-Co PBA). Results indicate that the dramatic enhancement of BPA degradation could be partly attributed to the induced homogeneous Fenton reaction by the enhanced dissolution of Fe-III-Co PBA. Meanwhile, the Hz coordinated iron site (H2NH2N-Fe), which is evolved from the original water coordinated iron site (H2O-Fe), was identified as the main active site. A possible reaction pathway involving the proposed active iron species was proposed. (C) 2016 Elsevier B.V. All rights reserved.
WOS关键词ORGANIC POLLUTANTS ; ELECTRON-TRANSFER ; NEUTRAL PH ; VISIBLE IRRADIATION ; REACTION-MECHANISM ; HYDROXYL RADICALS ; IRON ; DEGRADATION ; SYSTEM ; REMOVAL
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000371186900008
出版者ELSEVIER SCIENCE BV
源URL[http://cas-ir.dicp.ac.cn/handle/321008/171020]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Wang, Junhu
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Li, Xuning,Rykov, Alexandre I.,Wang, Junhu. Hydrazine drastically promoted Fenton oxidation of bisphenol A catalysed by a Fe-III-Co Prussian blue analogue[J]. CATALYSIS COMMUNICATIONS,2016,77:32-36.
APA Li, Xuning,Rykov, Alexandre I.,&Wang, Junhu.(2016).Hydrazine drastically promoted Fenton oxidation of bisphenol A catalysed by a Fe-III-Co Prussian blue analogue.CATALYSIS COMMUNICATIONS,77,32-36.
MLA Li, Xuning,et al."Hydrazine drastically promoted Fenton oxidation of bisphenol A catalysed by a Fe-III-Co Prussian blue analogue".CATALYSIS COMMUNICATIONS 77(2016):32-36.

入库方式: OAI收割

来源:大连化学物理研究所

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