Hydrazine drastically promoted Fenton oxidation of bisphenol A catalysed by a Fe-III-Co Prussian blue analogue
文献类型:期刊论文
作者 | Li, Xuning1,2; Rykov, Alexandre I.1; Wang, Junhu1 |
刊名 | CATALYSIS COMMUNICATIONS
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出版日期 | 2016-03-05 |
卷号 | 77页码:32-36 |
关键词 | Reducing Agent Fenton Mechanism Hz Coordinated Iron Site Mossbauer Spectroscopy |
ISSN号 | 1566-7367 |
DOI | 10.1016/j.catcom.2016.01.004 |
文献子类 | Article |
英文摘要 | Herein, for the first time it has been demonstrated that hydrazine (Hz) could significantly promote the bisphenol A (BPA) degradation in the Fenton reaction catalysed by Fe[Co(CN)(6)]center dot 2H(2)O Prussian blue analogue (Fe-III-Co PBA). Results indicate that the dramatic enhancement of BPA degradation could be partly attributed to the induced homogeneous Fenton reaction by the enhanced dissolution of Fe-III-Co PBA. Meanwhile, the Hz coordinated iron site (H2NH2N-Fe), which is evolved from the original water coordinated iron site (H2O-Fe), was identified as the main active site. A possible reaction pathway involving the proposed active iron species was proposed. (C) 2016 Elsevier B.V. All rights reserved. |
WOS关键词 | ORGANIC POLLUTANTS ; ELECTRON-TRANSFER ; NEUTRAL PH ; VISIBLE IRRADIATION ; REACTION-MECHANISM ; HYDROXYL RADICALS ; IRON ; DEGRADATION ; SYSTEM ; REMOVAL |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000371186900008 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171020] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Wang, Junhu |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Xuning,Rykov, Alexandre I.,Wang, Junhu. Hydrazine drastically promoted Fenton oxidation of bisphenol A catalysed by a Fe-III-Co Prussian blue analogue[J]. CATALYSIS COMMUNICATIONS,2016,77:32-36. |
APA | Li, Xuning,Rykov, Alexandre I.,&Wang, Junhu.(2016).Hydrazine drastically promoted Fenton oxidation of bisphenol A catalysed by a Fe-III-Co Prussian blue analogue.CATALYSIS COMMUNICATIONS,77,32-36. |
MLA | Li, Xuning,et al."Hydrazine drastically promoted Fenton oxidation of bisphenol A catalysed by a Fe-III-Co Prussian blue analogue".CATALYSIS COMMUNICATIONS 77(2016):32-36. |
入库方式: OAI收割
来源:大连化学物理研究所
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