Hydrogen Intercalation of Graphene and Boron Nitride Monolayers Grown on Pt(111)
文献类型:期刊论文
作者 | Wei, Mingming1; Fu, Qiang1; Wu, Hao1,2; Dong, Aiyi1; Bao, Xinhe1 |
刊名 | TOPICS IN CATALYSIS
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出版日期 | 2016-03-01 |
卷号 | 59期号:5-7页码:543-549 |
关键词 | Graphene Hexagonal Boron Nitride Pt(111) Intercalation Photoemission Spectroscopy |
ISSN号 | 1022-5528 |
DOI | 10.1007/s11244-015-0516-4 |
文献子类 | Article |
英文摘要 | H-2 atmosphere is often involved in growth and application of two-dimensional (2D) atomic crystals, and it is of great importance to understand interaction of the 2D materials with H-2 molecules. Here, a full graphene layer and a full hexagonal boron nitride (h-BN) layer grown on Pt(111) were exposed to H-2 atmosphere, which were investigated by in situ near ambient pressure X-ray photoelectron spectroscopy and quasi in situ ultraviolet photoelectron spectroscopy. We confirm the occurrence of hydrogen intercalation of the graphene and h-BN overlayers in ambient pressure H-2. The hydrogen intercalation in 0.1 Torr H-2 at room temperature and hydrogen desorption in 0.1 Torr H-2 at 200 A degrees C are fully reversible on the graphene/Pt(111) and h-BN/Pt(111) surfaces. Furthermore, hydrogen desorption on the graphene/Pt(111) and h-BN/Pt(111) surfaces was found to happen at lower temperature than that on the Pt(111) surface due to the graphene and h-BN cover effect. |
WOS关键词 | METAL-CATALYZED REACTIONS ; EPITAXIAL GRAPHENE ; AMBIENT-PRESSURE ; PHOTOELECTRON-SPECTROSCOPY ; REVERSIBLE HYDROGENATION ; OXYGEN INTERCALATION ; H-BN ; SURFACE ; ADSORPTION ; COVER |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000371424800014 |
出版者 | SPRINGER/PLENUM PUBLISHERS |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171050] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Fu, Qiang |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China |
推荐引用方式 GB/T 7714 | Wei, Mingming,Fu, Qiang,Wu, Hao,et al. Hydrogen Intercalation of Graphene and Boron Nitride Monolayers Grown on Pt(111)[J]. TOPICS IN CATALYSIS,2016,59(5-7):543-549. |
APA | Wei, Mingming,Fu, Qiang,Wu, Hao,Dong, Aiyi,&Bao, Xinhe.(2016).Hydrogen Intercalation of Graphene and Boron Nitride Monolayers Grown on Pt(111).TOPICS IN CATALYSIS,59(5-7),543-549. |
MLA | Wei, Mingming,et al."Hydrogen Intercalation of Graphene and Boron Nitride Monolayers Grown on Pt(111)".TOPICS IN CATALYSIS 59.5-7(2016):543-549. |
入库方式: OAI收割
来源:大连化学物理研究所
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