Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere
文献类型：期刊论文
| 作者 | Wang, Lianyue1; Shang, SenSen1,2; Li, Guosong1; Ren, Lanhui1,2; Lv, Ying1; Gao, Shuang1 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2016-03-04 |
| 卷号 | 81期号:5页码:2189-2193 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.6b00009 |
| 文献子类 | Article |
| 英文摘要 | We report a new Fe(NO3)(3)center dot 9H(2)O/9-azabicyclo-[3.3.1]nonan-N-oxyl catalyst system that enables efficient aerobic oxidation of a broad range of primary and secondary alcohols to the corresponding aldehydes and ketones at room temperature with ambient air as the oxidant. The catalyst system exhibits excellent activity and selectivity for primary aliphatic alcohol oxidation. This procedure can also be scaled up. Kinetic analysis demonstrates that C-H bond cleavage is the rate-determining step and that cationic species are involved in the reaction. |
| WOS关键词 | SECONDARY BENZYLIC ALCOHOLS ; MOLECULAR-OXYGEN ; ROOM-TEMPERATURE ; MILD CONDITIONS ; PROPARGYLIC ALCOHOLS ; CARBONYL-COMPOUNDS ; ORGANIC-SYNTHESIS ; ALDEHYDES ; EFFICIENT ; IRON |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000371753900051 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171056]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gao, Shuang |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Lianyue,Shang, SenSen,Li, Guosong,et al. Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(5):2189-2193. |
| APA | Wang, Lianyue,Shang, SenSen,Li, Guosong,Ren, Lanhui,Lv, Ying,&Gao, Shuang.(2016).Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere.JOURNAL OF ORGANIC CHEMISTRY,81(5),2189-2193. |
| MLA | Wang, Lianyue,et al."Iron/ABNO-Catalyzed Aerobic Oxidation of Alcohols and Ketones under Ambient Atmosphere".JOURNAL OF ORGANIC CHEMISTRY 81.5(2016):2189-2193. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。