Development of a Continuous-Flow Microreactor for Asymmetric Sulfoxidation Using a Biomimetic Manganese Catalyst
文献类型：期刊论文
| 作者 | Dai, Wen1,2; Mi, Yuan1,2; Lv, Ying1,2; Chen, Bo1,2; Li, Guosong1,2; Chen, Guangwen1,2; Gao, Shuang1,2 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2016-02-18 |
| 卷号 | 358期号:4页码:667-671 |
| 关键词 | Asymmetric Sulfoxidation Biomimetic Process Continuous Flow Conditions Microreactor Porphyrin-inspired Catalyst |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.201501023 |
| 文献子类 | Article |
| 英文摘要 | Asymmetric sulfoxidation catalyzed by a biomimetic manganese complex under continuous-flow microreactor is described. The reaction is conducted in microreactor, it can rapidly (<4min) oxidize a wide scope of sulfides with high yield (up to 91%) and excellent enantioselectivity (up to 99% ee), and allows shorter reaction times, easier scale-up and lower catalyst loadings than its batchwise counterpart. Additionally, a convenient numbering-up strategy for the scale-up of asymmetric sulfoxidation has been developed which enables a direct scaling of the reaction to 5g affording the corresponding sulfoxides within 20min. |
| WOS关键词 | AQUEOUS HYDROGEN-PEROXIDE ; ENANTIOSELECTIVE SYNTHESIS ; OXIDATION CATALYSIS ; COMPLEX ; EPOXIDATION ; SULFIDES ; SYSTEM ; ORGANOCATALYSIS ; ALCOHOLS ; LIGANDS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000371665800021 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171062]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Chen, Guangwen; Gao, Shuang |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dai, Wen,Mi, Yuan,Lv, Ying,et al. Development of a Continuous-Flow Microreactor for Asymmetric Sulfoxidation Using a Biomimetic Manganese Catalyst[J]. ADVANCED SYNTHESIS & CATALYSIS,2016,358(4):667-671. |
| APA | Dai, Wen.,Mi, Yuan.,Lv, Ying.,Chen, Bo.,Li, Guosong.,...&Gao, Shuang.(2016).Development of a Continuous-Flow Microreactor for Asymmetric Sulfoxidation Using a Biomimetic Manganese Catalyst.ADVANCED SYNTHESIS & CATALYSIS,358(4),667-671. |
| MLA | Dai, Wen,et al."Development of a Continuous-Flow Microreactor for Asymmetric Sulfoxidation Using a Biomimetic Manganese Catalyst".ADVANCED SYNTHESIS & CATALYSIS 358.4(2016):667-671. |
入库方式： OAI收割
来源：大连化学物理研究所
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