Synthesis and Characterization of Phenothiazine-Based Platinum(II)-Acetylide Photosensitizers for Efficient Dye-Sensitized Solar Cells
文献类型：期刊论文
| 作者 | Siu, Chi-Ho5,6; Lee, Lawrence Tien Lin1; Yiu, Sze-Chun5,6; Ho, Po-Yu5,6; Zhou, Panwang2; Ho, Cheuk-Lam3,5,6; Chen, Tao1,4; Liu, Jianyong2; Han, Keli2; Wong, Wai-Yeung3,5,6 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2016-03-07 |
| 卷号 | 22期号:11页码:3750-3757 |
| 关键词 | Acetylide Dye-sensitized Solar Cells Phenothiazine Photosensitizers Platinum |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201503828 |
| 文献子类 | Article |
| 英文摘要 | Three new unsymmetrical phenothiazine-based platinum(II) bis(acetylide) complexes PT1-PT3 with different electron-donating arylacetylide ligands were synthesized and characterized. Their photophysical, electrochemical, and photovoltaic properties have been fully investigated and the density functional theory (DFT) calculations have been carried out. Under AM 1.5 irradiation (100mWcm(-2)), the PT1-based dye-sensitized solar cell (DSSC) device exhibited an attractive power conversion efficiency () up to 5.78%, with a short-circuit photocurrent density (J(sc)) of 10.98mAcm(-2), an open-circuit photovoltage (V-oc) of 0.738V, and a fill factor (ff) of 0.713. These findings provide strong evidence that platinum-acetylide complexes have great potential as promising photosensitizers in DSSC applications. |
| WOS关键词 | NANOCRYSTALLINE TITANIUM-DIOXIDE ; PLATINUM-ACETYLIDE POLYMERS ; POLYPYRIDYL COMPLEXES ; PHOTOVOLTAIC APPLICATIONS ; ANISOTROPIC DIELECTRICS ; CONJUGATED POLYMERS ; ELECTRON-TRANSFER ; CHARGE-TRANSPORT ; THIN-FILMS ; TIO2 |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000371741400029 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171078]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Ho, Cheuk-Lam; Chen, Tao; Han, Keli; Wong, Wai-Yeung |
| 作者单位 | 1.Chinese Univ Hong Kong, Dept Phys, Shatin, Hong Kong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116012, Peoples R China 3.HKBU Inst Res & Continuing Educ, Shenzhen Virtual Univ Pk, Shenzhen 518057, Peoples R China 4.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China 5.Hong Kong Baptist Univ, Inst Mol Funct Mat, Dept Chem, Partner State Key Lab Environm & Biol Anal, Waterloo Rd, Kowloon Tong, Hong Kong, Peoples R China 6.Hong Kong Baptist Univ, Waterloo Rd, Kowloon Tong, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Siu, Chi-Ho,Lee, Lawrence Tien Lin,Yiu, Sze-Chun,et al. Synthesis and Characterization of Phenothiazine-Based Platinum(II)-Acetylide Photosensitizers for Efficient Dye-Sensitized Solar Cells[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(11):3750-3757. |
| APA | Siu, Chi-Ho.,Lee, Lawrence Tien Lin.,Yiu, Sze-Chun.,Ho, Po-Yu.,Zhou, Panwang.,...&Wong, Wai-Yeung.(2016).Synthesis and Characterization of Phenothiazine-Based Platinum(II)-Acetylide Photosensitizers for Efficient Dye-Sensitized Solar Cells.CHEMISTRY-A EUROPEAN JOURNAL,22(11),3750-3757. |
| MLA | Siu, Chi-Ho,et al."Synthesis and Characterization of Phenothiazine-Based Platinum(II)-Acetylide Photosensitizers for Efficient Dye-Sensitized Solar Cells".CHEMISTRY-A EUROPEAN JOURNAL 22.11(2016):3750-3757. |
入库方式： OAI收割
来源：大连化学物理研究所
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