Low-temperature molar heat capacity and thermodynamic properties of rare earth complex
文献类型：期刊论文
| 作者 | Pan, Lu2; Gao, Xiao-Han2; Lv, Xue-Chuan2; Tan, Zhi-Cheng1 |
| 刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
 |
| 出版日期 | 2016-04-01 |
| 卷号 | 124期号:1页码:429-435 |
| 关键词 | Rare Earth Complex Structure Adiabatic Calorimetry Molar Heat Capacity |
| ISSN号 | 1388-6150 |
| DOI | 10.1007/s10973-015-5133-8 |
| 文献子类 | Article |
| 英文摘要 | A heptanuclear trigonal prismatic polyhedron, [EuCu6(mu-OH)(3)(Gly)(6)Im(6)](ClO4)(6)center dot 3H(2)O, was synthesized and characterized by elemental analysis and X-ray single-crystal diffraction. The complex crystallize is the rhombohedral R3 space group (a = b = 15.8673 a"<<, c = 23.4038 a"<<, V = 5103.0(6) a"<<(3), Z = 3). In the clusters, Eu3+ ions are situated in the center of a prism formed by six copper atoms and coordinate to nine oxygen atoms with a tricapped trigonal prismatic coordination polyhedron. Six glycinato ligands and six imidazole terminal ligands (each coordinates to one Cu2+) were used in the construction of the cluster. The low-temperature molar heat capacity, C (p,m), and thermodynamic properties of the complex were studied with an adiabatic calorimeter from 80 to 370 K. The thermodynamic functions [H (T)-H (298.15)] and [S (T)-S (298.15)] were derived in the temperature range from 80 to 370 K with a temperature interval of 5 K. The thermal properties of the complex from 300 to 800 K were studied by DSC and TG in nitrogen atmosphere. |
| WOS关键词 | THERMAL-EXPANSION ; COPPER(II) ; PEPTIDES ; POLYMERS |
| WOS研究方向 | Thermodynamics ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000372261900045 |
| 出版者 | SPRINGER |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171106]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Lv, Xue-Chuan |
| 作者单位 | 1.Chinese Acad Sci, Thermochem Lab, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Liaoning Shihua Univ, Sch Chem & Mat Sci, Coll Chem Engn & Environm, Fushun 113001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Lu,Gao, Xiao-Han,Lv, Xue-Chuan,et al. Low-temperature molar heat capacity and thermodynamic properties of rare earth complex[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2016,124(1):429-435. |
| APA | Pan, Lu,Gao, Xiao-Han,Lv, Xue-Chuan,&Tan, Zhi-Cheng.(2016).Low-temperature molar heat capacity and thermodynamic properties of rare earth complex.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,124(1),429-435. |
| MLA | Pan, Lu,et al."Low-temperature molar heat capacity and thermodynamic properties of rare earth complex".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 124.1(2016):429-435. |
入库方式： OAI收割
来源：大连化学物理研究所
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