Highly stable poly(ethylene glycol)-grafted alkaline anion exchange membranes
文献类型：期刊论文
| 作者 | Yang, Congrong1,2; Wang, Suli1; Ma, Wenjia1; Zhao, Shixiong1; Xu, Ziqi3; Sun, Gongquan1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:10页码:3886-3892 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c6ta00200e |
| 文献子类 | Article |
| 英文摘要 | A mechanically and chemically stable poly(ethylene glycol) (PEG)-grafted poly(styrene-ethylene-cobutylene-styrene) (SEBS)-based alkaline anion exchange membrane (AAEM) was designed, prepared and characterized. When subjected to tensile strain, the elongation at breaking of these SEBS-based AAEMs was up to 500%, a value 80 times greater than that of an AAEM using polystyrene as the main chain. Remarkably, the ion exchange capacity (IEC), conductivity, dimensions and mechanical properties of this AAEM could remain almost unchanged in 2.5 M KOH at 60 degrees C for about 3000 h, indicating the excellent alkaline stability of the PEG-grafted SEBS-based AAEMs. As confirmed by TEM, the grafting of PEG could enlarge the size of the ion-conducting channels, significantly enhancing the conductivity of these AAEMs (80 degrees C, from 29.2 mS cm(-1) to 51.9 mS cm(-1)). Furthermore, the peak power density of an H-2/O-2 single fuel cell using this SEBS-based AAEM was up to 146 mW cm(-2) at 50 degrees C. Based on these outstanding properties, this membrane has potential application not only for fuel cells, but also for other electrochemical energy conversion and storage devices, such as redox flow and alkaline ion batteries. |
| WOS关键词 | FUEL-CELLS ; BACKBONE DEGRADATION ; POLYMER ELECTROLYTES ; NMR-SPECTROSCOPY ; HEAD-GROUPS ; STABILITY ; CONDUCTIVITY ; QUATERNARY |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000371967000037 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171116]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Sun, Gongquan |
| 作者单位 | 1.Chinese Acad Sci, Div Fuel Cell & Battery, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Dalian Univ Technol, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Congrong,Wang, Suli,Ma, Wenjia,et al. Highly stable poly(ethylene glycol)-grafted alkaline anion exchange membranes[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(10):3886-3892. |
| APA | Yang, Congrong,Wang, Suli,Ma, Wenjia,Zhao, Shixiong,Xu, Ziqi,&Sun, Gongquan.(2016).Highly stable poly(ethylene glycol)-grafted alkaline anion exchange membranes.JOURNAL OF MATERIALS CHEMISTRY A,4(10),3886-3892. |
| MLA | Yang, Congrong,et al."Highly stable poly(ethylene glycol)-grafted alkaline anion exchange membranes".JOURNAL OF MATERIALS CHEMISTRY A 4.10(2016):3886-3892. |
入库方式： OAI收割
来源：大连化学物理研究所
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