Copper(I)-catalyzed olefination of N-sulfonylhydrazones with sulfones
文献类型：期刊论文
| 作者 | Xu, Shuai1; Gao, Yunpeng1; Chen, Ri1; Wang, Kang1; Zhang, Yan1; Wang, Jianbo1,2 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2016 |
| 卷号 | 52期号:24页码:4478-4480 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c6cc00444j |
| 文献子类 | Article |
| 英文摘要 | The Cu(I)-catalyzed olefination of N-sulfonylhydrazones with sulfones via metal carbene intermediates is reported. This reaction uses readily available startingmaterials and is operationally simple, thus representing a practical method for the construction of carbon-carbon double bonds. Mechanistically, Cu(I) carbene formation and subsequent carbene migratory insertion are proposed as the key steps. |
| WOS关键词 | H BOND FUNCTIONALIZATION ; CARBENE MIGRATORY INSERTION ; MODIFIED JULIA OLEFINATION ; METAL CARBENE ; CARBONYL-COMPOUNDS ; TOSYLHYDRAZONES ; METHYLENATION ; ALDEHYDES ; CONDENSATION ; DERIVATIVES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000372174700011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171124]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, BNLMS,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Shuai,Gao, Yunpeng,Chen, Ri,et al. Copper(I)-catalyzed olefination of N-sulfonylhydrazones with sulfones[J]. CHEMICAL COMMUNICATIONS,2016,52(24):4478-4480. |
| APA | Xu, Shuai,Gao, Yunpeng,Chen, Ri,Wang, Kang,Zhang, Yan,&Wang, Jianbo.(2016).Copper(I)-catalyzed olefination of N-sulfonylhydrazones with sulfones.CHEMICAL COMMUNICATIONS,52(24),4478-4480. |
| MLA | Xu, Shuai,et al."Copper(I)-catalyzed olefination of N-sulfonylhydrazones with sulfones".CHEMICAL COMMUNICATIONS 52.24(2016):4478-4480. |
入库方式： OAI收割
来源：大连化学物理研究所
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