中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation and characterization of a composite nanofiltration membrane interfacially polymerized from cis,cis-1,3,5-triaminocyclohexane and trimesoyl chloride

文献类型:期刊论文

作者Liu, Zhongnan1,2; Kuang, Wu1,2; Kang, Guodong2; Yu, Haijun2; Jin, Yan3; Zhou, Meiqing2; Liu, Dandan2; Cao, Yiming2
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2016-06-15
卷号133期号:23
关键词Membranes Polyamides Separation Techniques
ISSN号0021-8995
DOI10.1002/app.43511
文献子类Article
英文摘要cis,cis-1,3,5-Triaminocyclohexane (TAC) was synthesized and used to prepare composite nanofiltration (NF) membranes by interfacial polymerization with trimesoyl chloride (TMC). The surface elemental composition, morphology, and hydrophilicity of the prepared NF membranes were characterized. The separation performances were examined with various salts and polyethylene glycol (PEG400, PEG600) solutions. The effects of preparation conditions were also systematically studied. The NF membrane was negatively charged and exhibited a salt rejection in the order Na2SO4 (98.2%)>MgSO4 (90.8%)>MgCl2 (84.5%)>NaCl (54.6%). The water permeability was 1.56L m(-2) h(-1) bar(-1), and the molecular weight cutoff was 600 Da. The TAC/TMC membrane exhibited some characteristics that were different from the ones made from common diamines such as m-phenylenediamine: (1) the surface was smoother, without a ridge-and-valley structure; (2) there were two kinds of crosslinking points in the polyamide chains; (3) the active layer was formed faster (only 5 seconds was required to reach a Na2SO4 rejection of 98%). (c) 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43511.
WOS关键词REVERSE-OSMOSIS ; TETRAACYL CHLORIDE ; M-PHENYLENEDIAMINE ; PERFORMANCE ; MORPHOLOGY ; SUPPORT
WOS研究方向Polymer Science
语种英语
WOS记录号WOS:000372501900018
出版者WILEY-BLACKWELL
源URL[http://cas-ir.dicp.ac.cn/handle/321008/171128]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Cao, Yiming
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lib Clean Energy DNL, Dalian 116023, Peoples R China
3.Vontron Technol Co Ltd, Guiyang 550018, Peoples R China
推荐引用方式
GB/T 7714
Liu, Zhongnan,Kuang, Wu,Kang, Guodong,et al. Preparation and characterization of a composite nanofiltration membrane interfacially polymerized from cis,cis-1,3,5-triaminocyclohexane and trimesoyl chloride[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2016,133(23).
APA Liu, Zhongnan.,Kuang, Wu.,Kang, Guodong.,Yu, Haijun.,Jin, Yan.,...&Cao, Yiming.(2016).Preparation and characterization of a composite nanofiltration membrane interfacially polymerized from cis,cis-1,3,5-triaminocyclohexane and trimesoyl chloride.JOURNAL OF APPLIED POLYMER SCIENCE,133(23).
MLA Liu, Zhongnan,et al."Preparation and characterization of a composite nanofiltration membrane interfacially polymerized from cis,cis-1,3,5-triaminocyclohexane and trimesoyl chloride".JOURNAL OF APPLIED POLYMER SCIENCE 133.23(2016).

入库方式: OAI收割

来源:大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。