Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C-H Activation and Ring Opening
文献类型：期刊论文
| 作者 | Zhou, Xukai; Yu, Songjie; Kong, Lingheng; Li, Xingwei |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2016-02-01 |
| 卷号 | 6期号:2页码:647-651 |
| 关键词 | Rhodium(Iii) Catalysis C-h Activation Strained Ring Ring Opening Cyclopropanols |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.5b02414 |
| 文献子类 | Article |
| 英文摘要 | Rhodium-catalyzed C-H activation of arenes has been established as an important strategy for the rapid construction of new bonds. On the other hand, ring-opening of readily available cyclopropanols has served as a driving force for the coupling with various nucleophiles and electrophiles. Nevertheless, these two important areas evolved separately, and coupling of arenes with cyclopropanols via C-H activation has been rarely explored. In this work, the oxidative coupling between arenes and cyclopropanols has been realized with high efficiency and selectivity under Rh(III)-catalysis, providing an efficient route to access beta-aryl ketones. Moreover, the C-H bond has been extended to benzylic C-H bonds. |
| WOS关键词 | N-TYPE REACTIONS ; BOND ACTIVATION ; ALLYLIC ALCOHOLS ; INTERMOLECULAR AMIDATION ; C(SP(3))-H ACTIVATION ; CATALYZED ARYLATION ; EFFICIENT SYNTHESIS ; CONJUGATE ADDITION ; MILD CONDITIONS ; ARYL BROMIDES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000369774900017 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171158]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xukai,Yu, Songjie,Kong, Lingheng,et al. Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C-H Activation and Ring Opening[J]. ACS CATALYSIS,2016,6(2):647-651. |
| APA | Zhou, Xukai,Yu, Songjie,Kong, Lingheng,&Li, Xingwei.(2016).Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C-H Activation and Ring Opening.ACS CATALYSIS,6(2),647-651. |
| MLA | Zhou, Xukai,et al."Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C-H Activation and Ring Opening".ACS CATALYSIS 6.2(2016):647-651. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。