Rhodium(III)-catalyzed sp(2) C-H bond addition to CF3-substituted unsaturated ketones
文献类型：期刊论文
| 作者 | Jiang, Quanbin1; Guo, Tenglong1; Wu, Kaikai1; Yu, Zhengkun1,2 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2016 |
| 卷号 | 52期号:14页码:2913-2915 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c5cc10361d |
| 文献子类 | Article |
| 英文摘要 | Rhodium(III)-catalyzed conjugate addition of aromatic and olefinic C-H bonds to CF3-substituted unsaturated ketones was efficiently achieved. Both arene and olefin substrates bearing a chelate assisted-directing group were coupled with a variety of beta-trifluoromethyl-alpha,beta-unsaturated ketones with excellent atom-economy, high yields, and broad substrate scopes. |
| WOS关键词 | CONJUGATE ADDITION ; MILD CONDITIONS ; DIRECTING GROUP ; BETA,BETA-DISUBSTITUTED ENONES ; SELECTIVE FUNCTIONALIZATION ; ENANTIOSELECTIVE SYNTHESIS ; CONVERGENT SYNTHESIS ; ASYMMETRIC-SYNTHESIS ; FLUOROALKYL GROUP ; ACTIVATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000369641300009 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171168]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Zhengkun |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Quanbin,Guo, Tenglong,Wu, Kaikai,et al. Rhodium(III)-catalyzed sp(2) C-H bond addition to CF3-substituted unsaturated ketones[J]. CHEMICAL COMMUNICATIONS,2016,52(14):2913-2915. |
| APA | Jiang, Quanbin,Guo, Tenglong,Wu, Kaikai,&Yu, Zhengkun.(2016).Rhodium(III)-catalyzed sp(2) C-H bond addition to CF3-substituted unsaturated ketones.CHEMICAL COMMUNICATIONS,52(14),2913-2915. |
| MLA | Jiang, Quanbin,et al."Rhodium(III)-catalyzed sp(2) C-H bond addition to CF3-substituted unsaturated ketones".CHEMICAL COMMUNICATIONS 52.14(2016):2913-2915. |
入库方式： OAI收割
来源：大连化学物理研究所
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