Preparation of alumina nanoshell coated porous silica spheres for inorganic anions separation
文献类型：期刊论文
| 作者 | Song, Zhihua1,2; Wu, Dapeng2; Ding, Kun2; Guan, Yafeng2 |
| 刊名 | JOURNAL OF CHROMATOGRAPHY A
 |
| 出版日期 | 2016-02-12 |
| 卷号 | 1433页码:85-89 |
| 关键词 | Alumina Nanoshell Coated Mesoporous Silica Microbeads (Nanoal(2)o(3)/mesosio(2)) Ion Chromatography (Ic) Inorganic Anions |
| ISSN号 | 0021-9673 |
| DOI | 10.1016/j.chroma.2016.01.008 |
| 文献子类 | Article |
| 英文摘要 | It had been reported that alumina nanoshell coating could be obtained on the external surface of various substrates in one-nanometer precision in aqueous solution. In this work, alumina nanoshell coated mesoporous silica microbeads (nanoAl(2)O(3)/mesoSiO(2)) were prepared with the similar method, and were successfully applied to inorganic anions separation. As the mass transfer speed is largely constrained in the mesopore compared with that on the open surface, it was found that a complete alumina nanoshell coating could be obtained within the mesopore until the five-time coating was carried out. After characterization by BET, SEM and FTIR, it was found that the obtained nanoAl(2)O(3)/mesoSiO(2) particles are smooth and well dispersed, and the mesopores are well reserved. In addition, the full coverage of nanoAl(2)O(3) shell in mesopores was also confirmed by the binding capacity experiments with berberine. Finally, the nanoAl(2)O(3)/mesoSiO(2) particles were packed in silica capillary for the separation of inorganic anions I-, SCN-, Br-, NO2- and NO3- with ion chromatography (IC), and a column efficiency of 3.8 x 10(4) plates per meter was obtained for I-. (C) 2016 Published by Elsevier B.V. |
| WOS关键词 | PERFORMANCE LIQUID-CHROMATOGRAPHY ; PACKED CAPILLARY COLUMNS ; ZIRCONIA NANOPARTICLES ; HPLC ; PARTICLES ; TITANIA ; SUPPORT ; PHASES |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000370086300008 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171172]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Guan, Yafeng |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dept Instrumentat & Analyt Chem, Key Lab Separat Sci Analyt Chem, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Zhihua,Wu, Dapeng,Ding, Kun,et al. Preparation of alumina nanoshell coated porous silica spheres for inorganic anions separation[J]. JOURNAL OF CHROMATOGRAPHY A,2016,1433:85-89. |
| APA | Song, Zhihua,Wu, Dapeng,Ding, Kun,&Guan, Yafeng.(2016).Preparation of alumina nanoshell coated porous silica spheres for inorganic anions separation.JOURNAL OF CHROMATOGRAPHY A,1433,85-89. |
| MLA | Song, Zhihua,et al."Preparation of alumina nanoshell coated porous silica spheres for inorganic anions separation".JOURNAL OF CHROMATOGRAPHY A 1433(2016):85-89. |
入库方式： OAI收割
来源：大连化学物理研究所
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