Dimerization assembly mechanism involving proton coupled electron transfer for hydrogen evolution from water by molybdenum-oxo catalyst
文献类型：期刊论文
| 作者 | Zhang, Ming-Xing; Zhao, Guang-Jiu |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2016-04-15 |
| 卷号 | 664页码:439-443 |
| 关键词 | Hydrogen Evolution Dimerization Assembly Mechanism Proton-coupled Electron Transfer Hydrogen Bond Network |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2016.01.014 |
| 文献子类 | Article |
| 英文摘要 | In this work, the mechanism for hydrogen generation of a recently reported Mo-oxo catalyst is investigated by theoretical method. A novel dimerization assembly mechanism has been elaborated. Structural details of the Mo-oxo complex which are essential to the catalytic activity are provided. The dimerization mechanism of hydrogen production is demonstrated to be more feasible than the monomer mechanism proposed in the previous work. Furthermore, proton-coupled electron transfer (PCET) reaction in the hydrogen bond network after dimerization assembly plays a very significant role on the hydrogen evolution from water by molybdenum-oxo catalyst. This study can be useful in understanding of many catalytic processes for hydrogen generation and designing new catalysis with high efficiency. (C) 2016 Published by Elsevier B.V. |
| WOS关键词 | PLATINUM(II) TERPYRIDYL COMPLEXES ; INTRAMOLECULAR CHARGE-TRANSFER ; SENSITIZED SOLAR-CELLS ; LARGE STOKES SHIFT ; ACTIVE-SITE ; SUPRAMOLECULAR SYSTEMS ; FLUORESCENT SENSOR ; VISIBLE-LIGHT ; DIMER COMPLEX ; SELECTIVITY |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000369061700056 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171196]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhao, Guang-Jiu |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Ming-Xing,Zhao, Guang-Jiu. Dimerization assembly mechanism involving proton coupled electron transfer for hydrogen evolution from water by molybdenum-oxo catalyst[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2016,664:439-443. |
| APA | Zhang, Ming-Xing,&Zhao, Guang-Jiu.(2016).Dimerization assembly mechanism involving proton coupled electron transfer for hydrogen evolution from water by molybdenum-oxo catalyst.JOURNAL OF ALLOYS AND COMPOUNDS,664,439-443. |
| MLA | Zhang, Ming-Xing,et al."Dimerization assembly mechanism involving proton coupled electron transfer for hydrogen evolution from water by molybdenum-oxo catalyst".JOURNAL OF ALLOYS AND COMPOUNDS 664(2016):439-443. |
入库方式： OAI收割
来源：大连化学物理研究所
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