Rational design of photo-responsive supramolecular nanostructures based on an azobenzene-derived surfactant-encapsulated polyoxometalate complex
文献类型：期刊论文
| 作者 | Yu, Li3; Guo, Yongxian3; Gong, Yanjun3; Yu, Zhidan1; Gao, Yan'an2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:18页码:14468-14473 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c5ra27351j |
| 文献子类 | Article |
| 英文摘要 | Using an ionic self-assembly (ISA) approach, photo-responsive surfactant-encapsulated polyoxometalate complexes (SECs) were fabricated in water from an original Keggin-type polyoxometalate (POM) and a cationic surfactant containing an azobenzene group, viz. phosphotungstic acid (H-3[PW12O40]) and 4-ethyl-4'-(trimethylaminohexyloxy) azobenzene bromide (ETAB). The driving forces and self-assembly mechanism of the ETAB-POM supramolecular hybrids were investigated by NMR, Fourier transform infrared (FTIR), UV/vis and small angle X-ray scattering (SAXS) characterization methods. Of particular interest is the complex solution which shows an obvious variation upon UV light irradiation. On a macroscale, its turbidity increases obviously, from a clear solution before UV irradiation to a turbid state. The microcosmic structures of the complex change from coral-like structures to dispersive nanospheres. These phenomena can be ascribed to the transformation of ETAB from trans-to cis-isomers after exposure to UV light. Beyond that, a cyclic voltammetric (CV) method was employed to observe the electrochemical properties of SECs. The results obtained in this work will shed light of the SECs' applications in phase separation, heterogeneous catalysis reactions, the detection of environmental pollutants, etc. |
| WOS关键词 | ELECTROCHROMISM ; ASSEMBLIES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000369658100006 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171212]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Li |
| 作者单位 | 1.Shandong Univ, Sch Life Sci, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China 3.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Li,Guo, Yongxian,Gong, Yanjun,et al. Rational design of photo-responsive supramolecular nanostructures based on an azobenzene-derived surfactant-encapsulated polyoxometalate complex[J]. RSC ADVANCES,2016,6(18):14468-14473. |
| APA | Yu, Li,Guo, Yongxian,Gong, Yanjun,Yu, Zhidan,&Gao, Yan'an.(2016).Rational design of photo-responsive supramolecular nanostructures based on an azobenzene-derived surfactant-encapsulated polyoxometalate complex.RSC ADVANCES,6(18),14468-14473. |
| MLA | Yu, Li,et al."Rational design of photo-responsive supramolecular nanostructures based on an azobenzene-derived surfactant-encapsulated polyoxometalate complex".RSC ADVANCES 6.18(2016):14468-14473. |
入库方式： OAI收割
来源：大连化学物理研究所
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