A Highly Ion-Selective Zeolite Flake Layer on Porous Membranes for Flow Battery Applications
文献类型：期刊论文
| 作者 | Lu, Wenjing2,4; Zhang, Huamin2,3; Yuan, Zhizhang2,4; Zhu, Xiangxue5; Li, Mingrun1; Li, Xianfeng2,3 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-02-24 |
| 卷号 | 55期号:9页码:3058-3062 |
| 关键词 | Energy Storage Flow Batteries Pore Size Exclusion Porous Membranes Zsm-35 Zeolite |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201510849 |
| 文献子类 | Article |
| 英文摘要 | Zeolites are crystalline microporous aluminosilicates with periodic arrangements of cages and well-defined channels, which make them very suitable for separating ions of different sizes, and thus also for use in battery applications. Herein, an ultra-thin ZSM-35 zeolite flake was introduced onto a poly(ether sulfone) based porous membrane. The pore size of the zeolite (ca. 0.5nm) is intermediary between that of hydrated vanadium ions (>0.6nm) and protons (<0.24nm). The resultant membrane can thus be used to perfectly separate vanadium ions and protons, making this technology useful in vanadium flow batteries (VFB). A VFB with a zeolite-coated membrane exhibits a columbic efficiency of >99% and an energy efficiency of >81% at 200mAcm(-2), which is by far the highest value ever reported. These convincing results indicate that zeolite-coated membranes are promising in battery applications. |
| WOS关键词 | RESEARCH-AND-DEVELOPMENT ; EXCHANGE MEMBRANES ; FUEL-CELL ; ENERGY ; DEGRADATION ; SEPARATOR ; MECHANISM ; TRANSPORT ; PROGRESS ; STORAGE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000370656200013 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171236]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Huamin; Li, Xianfeng |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Div Energy Storage, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 5.Chinese Acad Sci, Div Fossil Energy Convers, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Wenjing,Zhang, Huamin,Yuan, Zhizhang,et al. A Highly Ion-Selective Zeolite Flake Layer on Porous Membranes for Flow Battery Applications[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(9):3058-3062. |
| APA | Lu, Wenjing,Zhang, Huamin,Yuan, Zhizhang,Zhu, Xiangxue,Li, Mingrun,&Li, Xianfeng.(2016).A Highly Ion-Selective Zeolite Flake Layer on Porous Membranes for Flow Battery Applications.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(9),3058-3062. |
| MLA | Lu, Wenjing,et al."A Highly Ion-Selective Zeolite Flake Layer on Porous Membranes for Flow Battery Applications".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.9(2016):3058-3062. |
入库方式： OAI收割
来源：大连化学物理研究所
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