Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons
文献类型：期刊论文
| 作者 | Li, Yanbang2; Gan, Liangbing1,2; Xu, Dan2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-02-12 |
| 卷号 | 55期号:7页码:2483-2487 |
| 关键词 | Amination Conjugation Fullerenes Nucleophilic Addition X-ray Diffraction |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201510872 |
| 文献子类 | Article |
| 英文摘要 | Secondary aliphatic amines add to a pole pentagon of [70] fullerene in the presence of N-fluorobenzenesulfonimide to form cyclopentadienyl-type adducts, C-70(NSO2Ph)( NR1R2) 4 (1), which can be converted into analogous C-70 derivatives such as C-70(NHSO2Ph)(NHTol) 5 (2). Further addition reactions of either 1 or 2 take place selectively at the opposite pole pentagon of the C-70 'cage, thus forming curved p systems with a reduced number of p electrons, and the products include a dodecakis-adduct with a Vogtle belt motif. |
| WOS关键词 | FULLERENE CHEMISTRY ; SOLAR-CELLS ; C-60 ; REGIOCHEMISTRY ; AMINE ; FUNCTIONALIZATION ; DERIVATIVES ; CYCLOPHANE ; COMPLEXES ; ADDITIONS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000369970500033 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171250]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gan, Liangbing |
| 作者单位 | 1.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yanbang,Gan, Liangbing,Xu, Dan. Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(7):2483-2487. |
| APA | Li, Yanbang,Gan, Liangbing,&Xu, Dan.(2016).Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(7),2483-2487. |
| MLA | Li, Yanbang,et al."Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.7(2016):2483-2487. |
入库方式： OAI收割
来源：大连化学物理研究所
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