Iodide-Promoted Dehydrogenation of Formic Acid on a Rhodium Complex
文献类型：期刊论文
| 作者 | Li, Can3; Xiao, Jianliang2; Wang, Zhijun1,2,3; Lu, Sheng-Mei3; Wu, Jianjun2 |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2016-02-01 |
| 期号 | 4页码:490-496 |
| 关键词 | Dehydrogenation Rhodium Homogeneous Catalysis Formic Acid Halides |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.201501061 |
| 文献子类 | Article |
| 英文摘要 | Efficient and simple catalyst systems for dehydrogenation of formic acid (FA) to produce hydrogen are always desirable. In this work, the catalytic dehydrogenation of FA to H-2 and CO2 by using the readily available [RhCp*Cl-2](2) was found to be accelerated simply by the addition of halide anions, iodide being the most effective. At 60 degrees C, with [RhCp*Cl-2](2) in azeotropic FA and triethylamine (TEA), the initial turnover frequency of dehydrogenation in the presence of I- (4375 h(-1)) is seven times as high as that of the reaction without additive (625 h(-1)). Preliminary mechanistic studies suggest that the dehydrogenation is turnover-limited by the hydride-formation step, which could be facilitated by the presence of I-. |
| WOS关键词 | CHEMICAL HYDROGEN STORAGE ; CATALYZED TRANSFER HYDROGENATION ; AMBIENT CONDITIONS ; ROOM-TEMPERATURE ; CARBON-DIOXIDE ; REVERSIBLE HYDROGENATION ; PD NANOPARTICLES ; IRON CATALYST ; EFFICIENT ; GENERATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000370352400005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171258]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Can; Xiao, Jianliang |
| 作者单位 | 1.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Univ Liverpool, Dept Chem, Liverpool Ctr Mat & Catalysis, Liverpool L69 7ZD, Merseyside, England 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Can,Xiao, Jianliang,Wang, Zhijun,et al. Iodide-Promoted Dehydrogenation of Formic Acid on a Rhodium Complex[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2016(4):490-496. |
| APA | Li, Can,Xiao, Jianliang,Wang, Zhijun,Lu, Sheng-Mei,&Wu, Jianjun.(2016).Iodide-Promoted Dehydrogenation of Formic Acid on a Rhodium Complex.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(4),490-496. |
| MLA | Li, Can,et al."Iodide-Promoted Dehydrogenation of Formic Acid on a Rhodium Complex".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .4(2016):490-496. |
入库方式： OAI收割
来源：大连化学物理研究所
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