Rhodium-Catalyzed C-S and C-N Functionalization of Arenes: Combination of C-H Activation and Hypervalent Iodine Chemistry
文献类型：期刊论文
| 作者 | Li, Xingwei; Yu, Xinzhang; Qi, Zisong; Wang, Fen |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2016-01-11 |
| 卷号 | 22期号:2页码:511-516 |
| 关键词 | C-h Activation Homogeneous Catalysis Hypervalent Iodine Rhodium Umpolung |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201504179 |
| 文献子类 | Article |
| 英文摘要 | Rhodium-catalyzed sulfonylation, thioetherification, thiocyanation, and other heterofunctionalizations of arenes bearing a heterocyclic directing group have been realized. The reaction proceeds by initial RhIII-catalyzed C-H hyperiodination of arene at room temperature followed by uncatalyzed nucleophilic functionalization. A diaryliodonium salt is isolated as an intermediate, which represents umpolung of the arene substrate, in contrast to previous studies that suggested umpolung of the coupling partner. |
| WOS关键词 | ONE-POT SYNTHESIS ; UNACTIVATED C(SP(3))-H BONDS ; DIARYLIODONIUM SALTS ; ARYLSULFONYL CHLORIDES ; CHELATION ASSISTANCE ; DIRECT SULFONYLATION ; ROOM-TEMPERATURE ; ARYL ; AMIDATION ; ARYLATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000368903200010 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171308]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xingwei,Yu, Xinzhang,Qi, Zisong,et al. Rhodium-Catalyzed C-S and C-N Functionalization of Arenes: Combination of C-H Activation and Hypervalent Iodine Chemistry[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(2):511-516. |
| APA | Li, Xingwei,Yu, Xinzhang,Qi, Zisong,&Wang, Fen.(2016).Rhodium-Catalyzed C-S and C-N Functionalization of Arenes: Combination of C-H Activation and Hypervalent Iodine Chemistry.CHEMISTRY-A EUROPEAN JOURNAL,22(2),511-516. |
| MLA | Li, Xingwei,et al."Rhodium-Catalyzed C-S and C-N Functionalization of Arenes: Combination of C-H Activation and Hypervalent Iodine Chemistry".CHEMISTRY-A EUROPEAN JOURNAL 22.2(2016):511-516. |
入库方式： OAI收割
来源：大连化学物理研究所
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