CO2 methanation over TiO2-Al2O3 binary oxides supported Ru catalysts
文献类型：期刊论文
| 作者 | Xu, Jinghua1,2; Lin, Qingquan3; Su, Xiong1; Duan, Hongmin1; Geng, Haoran2; Huang, Yanqiang1 |
| 刊名 | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| 出版日期 | 2016 |
| 卷号 | 24期号:1页码:140-145 |
| 关键词 | Co2 Methanation Supported Ru Catalyst Tio2-al2o3 Binary Oxide |
| ISSN号 | 1004-9541 |
| DOI | 10.1016/j.cjche.2015.07.002 |
| 文献子类 | Article |
| 英文摘要 | TiO2 modified Al2O3 binary oxide was prepared by a wet-impregnation method and used as the support for ruthenium catalyst. The catalytic performance of Ru/TiO2-Al2O3 catalyst in CO2 methanation reaction was investigated. Compared with Ru/Al2O3 catalyst, the Ru/TiO2-Al2O3 catalytic system exhibited a much higher activity in CO2 methanation reaction. The reaction rate over Ru/TiO2-Al2O3 was 0.59 mol CO2.(g Ru)(-1).h(-1), 3.1 times higher than that on Ru/Al2O3 [0.19 mol CO2.(g Ru)(-1).h(-1)]. The effect of TiO2 content and TiO2-Al2O3 calcination temperature on catalytic performance was addressed. The corresponding structures of each catalyst were characterized by means of H-2-TPR, XRD, and TEM. Results indicated that the averaged particle size of the Ru on TiO2-Al2O3 support is 2.8 nm, smaller than that on Al2O3 support of 4.3 nm. Therefore, we conclude that the improved activity over Ru/TiO2-Al2O3 catalyst is originated from the smaller particle size of ruthenium resulting from a strong interaction between Ru and the rutile-TiO2 support, which hindered the aggregation of Ru nanoparticles. (C)c 2015 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved. |
| WOS关键词 | HYDROGENATION ; PERFORMANCE ; NANOPARTICLES ; TIO2 ; EFFICIENCY |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000369695800019 |
| 出版者 | CHEMICAL INDUSTRY PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171364]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Geng, Haoran; Huang, Yanqiang |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Peoples R China 3.Yantai Univ, Sch Chem & Chem Engn, Shandong Appl Res Ctr Gold Nanotechnol Au SDARC, Yantai 264005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Jinghua,Lin, Qingquan,Su, Xiong,et al. CO2 methanation over TiO2-Al2O3 binary oxides supported Ru catalysts[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2016,24(1):140-145. |
| APA | Xu, Jinghua,Lin, Qingquan,Su, Xiong,Duan, Hongmin,Geng, Haoran,&Huang, Yanqiang.(2016).CO2 methanation over TiO2-Al2O3 binary oxides supported Ru catalysts.CHINESE JOURNAL OF CHEMICAL ENGINEERING,24(1),140-145. |
| MLA | Xu, Jinghua,et al."CO2 methanation over TiO2-Al2O3 binary oxides supported Ru catalysts".CHINESE JOURNAL OF CHEMICAL ENGINEERING 24.1(2016):140-145. |
入库方式： OAI收割
来源：大连化学物理研究所
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