Influence of pretreatment temperature on catalytic performance of rutile TiO2-supported ruthenium catalyst in CO2 methanation
文献类型：期刊论文
| 作者 | Xu, Jinghua2,3; Su, Xiong2; Duan, Hongmin2; Hou, Baolin2; Lin, Qingquan4; Liu, Xiaoyan2; Pan, Xiaoli2; Pei, Guangxian2; Geng, Haoran1; Huang, Yanqiang2 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2016 |
| 卷号 | 333页码:227-237 |
| ISSN号 | 0021-9517 |
| 关键词 | Co2 Methanation Ru Tio2 Xas Drifts |
| DOI | 10.1016/j.jcat.2015.10.025 |
| 文献子类 | Article |
| 英文摘要 | Catalytic hydrogenation of CO2 to methane was investigated over Ru/rutile TiO2, focusing on the influence of the pretreatment temperature on the activity. Rutile TiO2 stabilized Ru nanoparticles even after pretreatment at 800 degrees C; therefore it was possible to establish the structure-activity relationship without considering the particle size effect. The CO2 turnover frequency initially increased with increasing pretreatment temperature from 300 to 800 degrees C, and reached a maximum value of 1.59 s(-1) on Ru/rutile TiO2 pretreated at 600 degrees C; it decreased to 1.16 s(-1) for the sample pretreated at 800 degrees C. The characterization results indicated that the activity depended on both the extent of encapsulation of Ru particles by TiOx layers and the number of hydroxyl groups on the TiOx surface. The mechanism of CO2 methanation was discussed based on in situ diffuse-reflectance infrared Fourier-transform spectroscopy results. (C) 2015 Elsevier Inc. All rights reserved. |
| WOS关键词 | FISCHER-TROPSCH SYNTHESIS ; SUPPORTED RU CATALYSTS ; SURFACE-REACTION RATES ; CARBON-DIOXIDE ; HYDROGEN REDUCTION ; REACTION-MECHANISM ; RU/TIO2 CATALYST ; BOUNDARY SITES ; PARTICLE-SIZE ; RH CATALYSTS |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| WOS记录号 | WOS:000368568700022 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171418]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Huang, Yanqiang |
| 作者单位 | 1.Jinan Univ, Sch Mat Sci & Engn, 106 Jiwei Rd, Jinan 250022, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Shandong Univ, Sch Mat Sci & Engn, 17923 Jingshi Rd, Jinan 250061, Peoples R China 4.Yantai Univ, Sch Chem & Chem Engn, Shandong Appl Res Ctr Gold Nanotechnol Au SDARC, Yantai 264005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Jinghua,Su, Xiong,Duan, Hongmin,et al. Influence of pretreatment temperature on catalytic performance of rutile TiO2-supported ruthenium catalyst in CO2 methanation[J]. JOURNAL OF CATALYSIS,2016,333:227-237. |
| APA | Xu, Jinghua.,Su, Xiong.,Duan, Hongmin.,Hou, Baolin.,Lin, Qingquan.,...&Zhang, Tao.(2016).Influence of pretreatment temperature on catalytic performance of rutile TiO2-supported ruthenium catalyst in CO2 methanation.JOURNAL OF CATALYSIS,333,227-237. |
| MLA | Xu, Jinghua,et al."Influence of pretreatment temperature on catalytic performance of rutile TiO2-supported ruthenium catalyst in CO2 methanation".JOURNAL OF CATALYSIS 333(2016):227-237. |
入库方式： OAI收割
来源：大连化学物理研究所
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