Aromatic Dicupra[10]annulenes
文献类型：期刊论文
| 作者 | Wei, Junnian; Zhang, Yongliang; Chi, Yue; Liu, Liang; Zhang, Wen-Xiong; Xi, Zhenfeng1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2016-01-13 |
| 卷号 | 138期号:1页码:60-63 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.5b11317 |
| 文献子类 | Article |
| 英文摘要 | Metal-containing aromatic systems (metal-la-aromatics) are unique and important both experimentally and theoretically. Among metalla-aromatics, six-membered metallabenzenes and metallabenzynes have attracted much attention in recent years. However, reports on their superior homologues are rare. In this work, the first series of aromatic dicupra[10]annulenes were isolated from the reaction of dilithio reagents and copper salts. Single-crystal X-ray structural analysis revealed dicupra[10]annulenes with averaged bond lengths. Li-7 NMR spectra and theoretical calculations revealed considerable aromatic character. XPS data suggested that the oxidation state of Cu atom in dicupra[10]annulenes was more likely to be Cu(I), indicating that the dilithio moieties in dicupra[10]annulenes participated as noninnocent ligands. This work demonstrates a novel approach to construct macrocyclic metalla-aromatics. |
| WOS关键词 | STRUCTURAL-CHARACTERIZATION ; ORGANOMETALLIC-CHEMISTRY ; COPPER(I) COMPLEXES ; TRANSITION-METAL ; METALLABENZYNES ; LIGANDS ; STABILIZATION ; OSMAPENTALENE ; SUBSTITUENTS ; IRIDABENZENE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000368323100011 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171434]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Xi, Zhenfeng |
| 作者单位 | 1.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Junnian,Zhang, Yongliang,Chi, Yue,et al. Aromatic Dicupra[10]annulenes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2016,138(1):60-63. |
| APA | Wei, Junnian,Zhang, Yongliang,Chi, Yue,Liu, Liang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2016).Aromatic Dicupra[10]annulenes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,138(1),60-63. |
| MLA | Wei, Junnian,et al."Aromatic Dicupra[10]annulenes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138.1(2016):60-63. |
入库方式： OAI收割
来源：大连化学物理研究所
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