C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation
文献类型：期刊论文
| 作者 | Huang, Fei2; Liu, Zhuqing2; Yu, Zhengkun1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-01-18 |
| 卷号 | 55期号:3页码:862-875 |
| 关键词 | Alcohols Alkylation Borrowing Hydrogen Green Chemistry Transition Metals |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201507521 |
| 文献子类 | Review |
| 英文摘要 | Transition-metal-catalyzed C-alkylation of ketones and secondary alcohols, with alcohols, avoids use of organometallic or environmentally unfriendly alkylating agents by means of borrowing hydrogen (BH) or hydrogen autotransfer (HA) activation of the alcohol substrates. Water is formed as the only by-product, thus making the BH process atom-economical and environmentally benign. Diverse homogeneous and heterogeneous transition-metal catalysts, ketones, and alcohols can be used for this transformation, thus rendering the BH process promising for replacing those procedures that use traditional alkylating agents. This Minireview summarizes the advances during the last five years in transition-metal-catalyzed BH -alkylation of ketones, and -alkylation of secondary alcohols with alcohols. A discussion on the application of the BH strategy for C-C bond formation is included. |
| WOS关键词 | BORROWING HYDROGEN METHODOLOGY ; DIRECT ALPHA-ALKYLATION ; SOLVENT-FREE CONDITIONS ; N BOND FORMATION ; SECONDARY ALCOHOLS ; BETA-ALKYLATION ; MILD CONDITIONS ; ALLYLIC ALCOHOLS ; ACID DERIVATIVES ; IRIDIUM COMPLEX |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000368070000002 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171474]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Zhengkun |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Fei,Liu, Zhuqing,Yu, Zhengkun. C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(3):862-875. |
| APA | Huang, Fei,Liu, Zhuqing,&Yu, Zhengkun.(2016).C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(3),862-875. |
| MLA | Huang, Fei,et al."C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.3(2016):862-875. |
入库方式： OAI收割
来源：大连化学物理研究所
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