Production of Diethyl Terephthalate from Biomass-Derived Muconic Acid
文献类型：期刊论文
| 作者 | Lu, Rui1,2; Lu, Fang2; Chen, Jiazhi1,2; Yu, Weiqiang2; Huang, Qianqian1,2; Zhang, Junjie1,2; Xu, Jie2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-01-04 |
| 卷号 | 55期号:1页码:249-253 |
| 关键词 | Biomass Catalysis Cycloaddition Muconic Acid Terephthalic Acid |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201509149 |
| 文献子类 | Article |
| 英文摘要 | We report a cascade synthetic route to directly obtain diethyl terephthalate, a replacement for terephthalic acid, from biomass-derived muconic acid, ethanol, and ethylene. The process involves two steps: First, a substituted cyclohexene system is built through esterification and Diels-Alder reaction; then, a dehydrogenation reaction provides diethyl terephthalate. The key esterification reaction leads to improved solubility and modulates the electronic properties of muconic acid, thus promoting the Diels-Alder reaction with ethylene. With silicotungstic acid as the catalyst, nearly 100% conversion of muconic acid was achieved, and the cycloadducts were formed with more than 99.0% selectivity. The palladium-catalyzed dehydrogenation reaction preferentially occurs under neutral or mildly basic conditions. The total yield of diethyl terephthalate reached 80.6% based on the amount of muconic acid used in the two-step synthetic process. |
| WOS关键词 | ADIPIC ACID ; P-XYLENE ; CATALYZED DEOXYDEHYDRATION ; AEROBIC OXIDATION ; LACTIC-ACID ; ETHYLENE ; CONVERSION ; CYCLOADDITION ; AROMATICS ; CHEMICALS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000368065300029 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171484]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Lu, Fang |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Rui,Lu, Fang,Chen, Jiazhi,et al. Production of Diethyl Terephthalate from Biomass-Derived Muconic Acid[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(1):249-253. |
| APA | Lu, Rui.,Lu, Fang.,Chen, Jiazhi.,Yu, Weiqiang.,Huang, Qianqian.,...&Xu, Jie.(2016).Production of Diethyl Terephthalate from Biomass-Derived Muconic Acid.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(1),249-253. |
| MLA | Lu, Rui,et al."Production of Diethyl Terephthalate from Biomass-Derived Muconic Acid".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.1(2016):249-253. |
入库方式： OAI收割
来源：大连化学物理研究所
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