Ternary Amides Containing Transition Metals for Hydrogen Storage: A Case Study with Alkali Metal Amidozincates
文献类型：期刊论文
| 作者 | Cao, Hujun3; Richter, Theresia M. M.2; Pistidda, Claudio3; Chaudhary, Anna-Lisa3; Santoru, Antonio3; Gizer, Goekhan3; Niewa, Rainer2; Chen, Ping1; Klassen, Thomas3; Dornheim, Martin3 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2015-11-23 |
| 卷号 | 8期号:22页码:3777-3782 |
| 关键词 | Hydrides Hydrogen Storage Sorption Kinetics Ternary Amides Transition Metals |
| ISSN号 | 1864-5631 |
| DOI | 10.1002/cssc.201500990 |
| 文献子类 | Article |
| 英文摘要 | The alkali metal amidozincates Li-4[Zn(NH2)(4)](NH2)(2) and K-2[Zn(NH2)(4)] were, to the best of our knowledge, studied for the first time as hydrogen storage media. Compared with the LiNH2-2LiH system, both Li-4[Zn(NH2)(4)](NH2)(2)-12LiH and K-2[Zn(NH2)(4)]-8LiH systems showed improved rehydrogenation performance, especially K-2[Zn(NH2)(4)]-8LiH, which can be fully hydrogenated within 30s at approximately 230 degrees C. The absorption properties are stable upon cycling. This work shows that ternary amides containing transition metals have great potential as hydrogen storage materials. |
| WOS关键词 | N-H SYSTEM ; RECENT PROGRESS ; LITHIUM AMIDE ; HYDRIDE ; COMPLEX ; LIH ; DESORPTION ; RELEASE ; IMIDES ; NH3 |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000365752200006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171580]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Cao, Hujun |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Stuttgart, Inst Inorgan Chem, D-70569 Stuttgart, Germany 3.Helmholtz Zentrum Geesthacht, Inst Mat Res Mat Technol, D-21502 Geesthacht, Germany |
| 推荐引用方式 GB/T 7714 | Cao, Hujun,Richter, Theresia M. M.,Pistidda, Claudio,et al. Ternary Amides Containing Transition Metals for Hydrogen Storage: A Case Study with Alkali Metal Amidozincates[J]. CHEMSUSCHEM,2015,8(22):3777-3782. |
| APA | Cao, Hujun.,Richter, Theresia M. M..,Pistidda, Claudio.,Chaudhary, Anna-Lisa.,Santoru, Antonio.,...&Dornheim, Martin.(2015).Ternary Amides Containing Transition Metals for Hydrogen Storage: A Case Study with Alkali Metal Amidozincates.CHEMSUSCHEM,8(22),3777-3782. |
| MLA | Cao, Hujun,et al."Ternary Amides Containing Transition Metals for Hydrogen Storage: A Case Study with Alkali Metal Amidozincates".CHEMSUSCHEM 8.22(2015):3777-3782. |
入库方式： OAI收割
来源：大连化学物理研究所
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