Synergetic Effect of Ultrasmall Metal Clusters and Zeolites Promoting Hydrogen Generation
文献类型：期刊论文
| 作者 | Wang, Ning1; Bai, Risheng1; Sun, Qiming1; Hui, Yu2; Zhang, Tianjun1; Do, David A.3; Zhang, Peng3; Song, Lijuan2; Miao, Shu4; Yu, Jihong1,5 |
| 刊名 | ADVANCED SCIENCE
 |
| 出版日期 | 2019-05-17 |
| 卷号 | 6期号:10页码:9 |
| ISSN号 | 2198-3844 |
| 关键词 | ammonia borane heterogeneous catalysis hydrogen evolution metal clusters zeolites |
| DOI | 10.1002/advs.201802350 |
| 通讯作者 | Yu, Jihong(jihong@jlu.edu.cn) |
| 英文摘要 | Taking advantage of the synergetic effect of confined ultrasmall metal clusters and zeolite frameworks is an efficient strategy for improving the catalytic performance of metal nanocatalysts. Herein, it is demonstrated that the synergetic effect of ultrasmall ruthenium (Ru) clusters and intrinsic Bronsted acidity of zeolite frameworks can significantly promote the hydrogen generation of ammonia borane (AB) hydrolysis. Ultrasmall Ru clusters are embedded onto the silicoaluminophosphate SAPO-34 (CHA) and various aluminosilicate zeolites (MFI, *BEA, and FAU) with tunable acidities by a facile incipient wetness impregnation method. Evidenced by high-resolution scanning transmission electron microscopy, the sub-nanometric Ru clusters are uniformly distributed throughout the zeolite crystals. The X-ray absorption spectroscopy measurements reveal the existence of Ru-H species between Ru clusters and adjacent Bronsted acid sites of zeolites, which could synergistically activate AB and water molecules, significantly enhancing the hydrogen evolution rate of AB hydrolysis. Notably, the Ru/SAPO-34-0.8Si (Si/Al = 0.8) and Ru/FAU (Si/Al = 30) catalysts with strong acidities afford high turnover frequency values up to 490 and 627 min(-1), respectively. These values are more than a 13-fold enhancement than that of the commercial Ru/C catalyst, and among the top level over other heterogeneous catalysts tested under similar conditions. |
| WOS关键词 | HIGHLY EFFICIENT CATALYST ; HYDROLYTIC DEHYDROGENATION ; AMMONIA-BORANE ; RUTHENIUM NANOPARTICLES ; ACTIVE CATALYST ; STORAGE ; CO ; TRANSFORMATION ; PERFORMANCE ; CHABAZITE |
| 资助项目 | National Key Research and Development Program of China[2016YFB0701100] ; National Natural Science Foundation of China[21835002] ; National Natural Science Foundation of China[21621001] ; 111 Project[B17020] ; U.S. DOE[DE-AC02-06CH11357] ; Canadian Light Source and its funding partners |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| 出版者 | WILEY |
| WOS记录号 | WOS:000468187200001 |
| 资助机构 | National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; U.S. DOE ; U.S. DOE ; Canadian Light Source and its funding partners ; Canadian Light Source and its funding partners ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; U.S. DOE ; U.S. DOE ; Canadian Light Source and its funding partners ; Canadian Light Source and its funding partners ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; U.S. DOE ; U.S. DOE ; Canadian Light Source and its funding partners ; Canadian Light Source and its funding partners ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; U.S. DOE ; U.S. DOE ; Canadian Light Source and its funding partners ; Canadian Light Source and its funding partners |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171829]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Jihong |
| 作者单位 | 1.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, 2699 Qianjin St, Changchun 130012, Jilin, Peoples R China 2.Liaoning Shihua Univ, Key Lab Petrochem Catalyt Sci & Technol Liaoning, Fushun 113001, Peoples R China 3.Dalhousie Univ, Dept Chem, Halifax, NS B3H 4R2, Canada 4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 5.Jilin Univ, Int Ctr Future Sci, 2699 Qianjin St, Changchun 130012, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Ning,Bai, Risheng,Sun, Qiming,et al. Synergetic Effect of Ultrasmall Metal Clusters and Zeolites Promoting Hydrogen Generation[J]. ADVANCED SCIENCE,2019,6(10):9. |
| APA | Wang, Ning.,Bai, Risheng.,Sun, Qiming.,Hui, Yu.,Zhang, Tianjun.,...&Yu, Jihong.(2019).Synergetic Effect of Ultrasmall Metal Clusters and Zeolites Promoting Hydrogen Generation.ADVANCED SCIENCE,6(10),9. |
| MLA | Wang, Ning,et al."Synergetic Effect of Ultrasmall Metal Clusters and Zeolites Promoting Hydrogen Generation".ADVANCED SCIENCE 6.10(2019):9. |
入库方式： OAI收割
来源：大连化学物理研究所
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