Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway
文献类型：期刊论文
| 作者 | Zhou, Xiao-Le1,2; Yang, Fan1; Sun, Han-Li1; Yin, Yun-Nian1; Ye, Wei-Ting1; Zhu, Rong1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2019-05-08 |
| 卷号 | 141期号:18页码:7250-7255 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.9b01857 |
| 通讯作者 | Zhu, Rong(rongzhu@pku.edu.cn) |
| 英文摘要 | A functional group tolerant cobalt-catalyzed method for the intermolecular hydrofunctionalization of alkenes with oxygen- and nitrogen-based nucleophiles is reported. This protocol features a strategic use of hypervalent iodine(III) reagents that enables a mechanistic shift from conventional cobalt-hydride catalysis. Key evidence was found supporting a unique bimetallic-mediated rate-limiting step involving two distinct cobalt(III) species, from which a new carbon-heteroatom bond is formed. |
| WOS关键词 | MARKOVNIKOV-SELECTIVE HYDROFUNCTIONALIZATION ; HETEROATOM BOND FORMATION ; UNACTIVATED OLEFINS ; ELECTRON-TRANSFER ; CARBOXYLIC-ACIDS ; OXIDATION ; HYDROAMINATION ; COMPLEXES ; FE ; ORGANOCOBALT(IV) |
| 资助项目 | College of Chemistry and Molecular Engineering, Peking University ; BNLMS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000467781600006 |
| 资助机构 | College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS ; College of Chemistry and Molecular Engineering, Peking University ; College of Chemistry and Molecular Engineering, Peking University ; BNLMS ; BNLMS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/171837]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhu, Rong |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol ABCT, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xiao-Le,Yang, Fan,Sun, Han-Li,et al. Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2019,141(18):7250-7255. |
| APA | Zhou, Xiao-Le,Yang, Fan,Sun, Han-Li,Yin, Yun-Nian,Ye, Wei-Ting,&Zhu, Rong.(2019).Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,141(18),7250-7255. |
| MLA | Zhou, Xiao-Le,et al."Cobalt-Catalyzed Intermolecular Hydrofunctionalization of Alkenes: Evidence for a Bimetallic Pathway".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 141.18(2019):7250-7255. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。