The Solution of Non-Linear Function of Ion Mobility Based on FAIMS Spectrum Peak Position
文献类型:期刊论文
作者 | Wu Zhi-yuan1; Yu Jian-wen1,2; Liu You-jiang1![]() |
刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
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出版日期 | 2017-10-01 |
卷号 | 37期号:10页码:3170-3174 |
关键词 | Chlorobenzenes VOCs Isomeride Ultra violet ion source Field asymmetric waveform ion mobility spectrometry |
ISSN号 | 1000-0593 |
DOI | 10.3964/j.issn.1000-0593(2017)10-3170-05 |
通讯作者 | Chen Chi-lai(chlchen@iim.ac.cn) |
英文摘要 | Volatile chlorobenzenes (CBs) is an organic pollutant which exists ubiquitously in the environment. Ion Mobility Spectrometry (IMS) has been a powerful technique for quick ion-separation and detection under ambient pressure. In this paper, atmospheric chlorobenzene, p-dichlorobenzene, o-dichlorobenzene and m-dichlorobenzene were detected by a homemade Vacuum Ultraviolet Field Asymmetric Waveform Ion Mobility Spectrometry (UV-FAIMS). The CV-I spectra under different Dispersion Voltage (DV) were obtained, then the CV-DV fingerprints spectra of the four substances were synthetized. Base on the fingerprint spectra, optimal separation and detection parameters of three isomers: dichlorobenzene, o-dichlorobenzene, m-dichlorobenzene were determined. The results showed that under the DV of 800 and 1 000 V, three substances could be effectively identified at CV of 20.4 V (DV=800 V), 3. 2 V(DV=800 V) and 11. 9 V(DV=1 000 V), respectively, by selecting the characteristic peaks. The influences of flow rate on FWHM and peak position of FAIMS spectrum were studied and the results provided a reference for flow optimization. The limit of detection (LOD) of UV-FAIMS investigated by using different concentrations of dichlorobenzene at DV=450 V and CV=4. 3V was lower than 0. 05 mg . m(-3). This paper provides a rapid and accurate detection method for halogenated benzene pollutant and other isomers of benzene. |
WOS关键词 | SPECTROSCOPY ; SELECTIVITY ; TECHNOLOGY ; PROGRESS |
WOS研究方向 | Spectroscopy |
语种 | 英语 |
WOS记录号 | WOS:000413888200035 |
出版者 | OFFICE SPECTROSCOPY & SPECTRAL ANALYSIS |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/35789] ![]() |
专题 | 合肥物质科学研究院_中科院合肥智能机械研究所 |
通讯作者 | Chen Chi-lai |
作者单位 | 1.Chinese Acad Sci, Inst Intelligent Machines, State Key Lab Transducer Technol, Hefei 230031, Anhui, Peoples R China 2.Hefei Univ Technol, Sch Mech Engn, Hefei 230009, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Wu Zhi-yuan,Yu Jian-wen,Liu You-jiang,et al. The Solution of Non-Linear Function of Ion Mobility Based on FAIMS Spectrum Peak Position[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2017,37(10):3170-3174. |
APA | Wu Zhi-yuan,Yu Jian-wen,Liu You-jiang,&Chen Chi-lai.(2017).The Solution of Non-Linear Function of Ion Mobility Based on FAIMS Spectrum Peak Position.SPECTROSCOPY AND SPECTRAL ANALYSIS,37(10),3170-3174. |
MLA | Wu Zhi-yuan,et al."The Solution of Non-Linear Function of Ion Mobility Based on FAIMS Spectrum Peak Position".SPECTROSCOPY AND SPECTRAL ANALYSIS 37.10(2017):3170-3174. |
入库方式: OAI收割
来源:合肥物质科学研究院
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