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Chinese Academy of Sciences Institutional Repositories Grid
Jinshajiangite: structure, twinning and pseudo-symmetry

文献类型:期刊论文

作者Jin Shiyun;  Xu Huifang;  Lee Seungyeol;  Fu Pingqiu
刊名Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials
出版日期2018
卷号74页码:325-336
关键词: Jinshajiangite Pseudosymmetry Perraultite Bafertisite Polytype Bobshannonite
英文摘要

The crystal structure of jinshajiangite based on a sample from its original discovery location is studied using single-crystal X-ray diffraction and transmission electron microscopy methods. Jinshajiangite is a titanium silicate mineral with an ideal chemical formula of BaNaFe4Ti2(Si2O7)( 2)O-2 (OH) 2 F. The structure of jinshajiangite is of P (1) over bar symmetry (triclinic system), with a = 8.7331 (2) angstrom, b = 8.7366 (2) angstrom, c = 11.0404 (3) angstrom, alpha = 81.477 (1)degrees, beta = 110.184 (1)degrees, gamma = 104.384 (1)degrees and V = 764.03 (3) angstrom(3), instead of the previously proposed C (1) over bar cell [a = 10.7059 (5) angstrom, b = 13.7992 (7) angstrom, c = 20.760 (1) angstrom, alpha = 90.008 (1)degrees, beta = 94.972 (1)degrees, gamma = 89.984 (1)degrees, V = 3055.4 (4)angstrom(3)]. The basic topology of the new structure is similar to the previously proposed C (1) over bar structure, except there is only one type of titanium silicate and intermediate cation layer in the structure (instead of two types), which are all related by the translation along the c-axis. Even though there is a significant amount of Mn in the chemical composition, no obvious ordering between Fe and Mn is observed in the structure. All the mineral species of the perraultite-type structure (jinshajiangite, perraultite, surkhobite and bobshannonite) should have the same P (1) over bar structure as jinshajiangite with similar to 10 angstrom d(001) spacing, and all the previously proposed monoclinic space groups were pseudosymmetry generated by nanoscale polysynthetic twinning on the (001) composition plane. The similar phenomenon observed in bafertisite is also discussed in the paper with an alternative polytype structure model proposed.

语种英语
源URL[http://ir.gyig.ac.cn/handle/42920512-1/8848]  
专题地球化学研究所_矿床地球化学国家重点实验室
作者单位1.Department of Geoscience, University of Wisconsin–Madison, 1215 W. Dayton Street, Madison, WI 53706, USA
2.Institute of Geochemistry at Guiyang, Chinese Academy of Science, Guiyang, Guizhou, People’s Republic of China.
推荐引用方式
GB/T 7714
Jin Shiyun;Xu Huifang;Lee Seungyeol;Fu Pingqiu. Jinshajiangite: structure, twinning and pseudo-symmetry[J]. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials,2018,74:325-336.
APA Jin Shiyun;Xu Huifang;Lee Seungyeol;Fu Pingqiu.(2018).Jinshajiangite: structure, twinning and pseudo-symmetry.Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials,74,325-336.
MLA Jin Shiyun;Xu Huifang;Lee Seungyeol;Fu Pingqiu."Jinshajiangite: structure, twinning and pseudo-symmetry".Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 74(2018):325-336.

入库方式: OAI收割

来源:地球化学研究所

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