Electrodeposition of gold nanoparticles on Cu-based metal-organic framework for the electrochemical detection of nitrite
文献类型：期刊论文
| 作者 | Chen, Huaiyin1,2; Yang, Tao3; Liu, Faqian3; Li, Weihua1,3 |
| 刊名 | SENSORS AND ACTUATORS B-CHEMICAL
 |
| 出版日期 | 2019-05-01 |
| 卷号 | 286页码:401-407 |
| ISSN号 | 0925-4005 |
| 关键词 | Metal-organic framework Au nanoparticles Nitrite Electrochemical detection Electrodeposition |
| DOI | 10.1016/j.snb.2018.10.036 |
| 通讯作者 | Li, Weihua(ytlwh666@163.com) |
| 英文摘要 | Herein, an electrochemical sensing platform based on Cu-based metal-organic framework (Cu-MOF) decorated with gold nanoparticles (AuNPs) is constructed for the sensitive detection of nitrite. Cu-MOF was synthesized by a simple wet chemical synthesis at room temperature. AuNPs were electrodeposited on Cu-MOF modified glass carbon electrode (Cu-MOF/GCE) using potentiostatic method. The AuNPs decorated Cu-MOF (Cu-MOF/Au) displays synergetic catalytic effect for the oxidation of nitrite due to the large surface area and porosity of Cu-MOF, which could prevent the aggregation of AuNPs and increase the adsorption of nitrite, combining with the high conductivity and excellent catalytic activity of AuNPs. A nitrite sensing platform was constructed based on Cu-MOF/Au/GCE, and amperometric technique was adopted for quantitative determination of nitrite. The prepared electrochemical sensing platform demonstrates high sensitivity, selectivity and good stability for the detection of nitrite. It shows two wide linear ranges of 0.1-4000 and 4000-10000 mu M, and the low detection limit of 82 nM. Moreover, the sensing platform can also be used for the nitrite detection in real samples. This work would broaden the application of MOFs material in constructing more novel electrochemical sensing platforms. |
| 资助项目 | National Natural Science Foundation of China[21675092] ; National Natural Science Foundation of China[41476083] ; National Natural Science Foundation of China[51525903] ; National Natural Science Foundation of China[21275084] ; Aoshan Talents Outstanding Scientist Program - Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-OS09] ; National Defense Scientific Research Cultivation Special Program of Sun Yat-sen University |
| WOS研究方向 | Chemistry ; Electrochemistry ; Instruments & Instrumentation |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE SA |
| WOS记录号 | WOS:000459129600053 |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/155566]  |
| 专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
| 通讯作者 | Li, Weihua |
| 作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Sun Yat Sen Univ, Sch Chem Engn & Technol, Zhuhai 519082, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Huaiyin,Yang, Tao,Liu, Faqian,et al. Electrodeposition of gold nanoparticles on Cu-based metal-organic framework for the electrochemical detection of nitrite[J]. SENSORS AND ACTUATORS B-CHEMICAL,2019,286:401-407. |
| APA | Chen, Huaiyin,Yang, Tao,Liu, Faqian,&Li, Weihua.(2019).Electrodeposition of gold nanoparticles on Cu-based metal-organic framework for the electrochemical detection of nitrite.SENSORS AND ACTUATORS B-CHEMICAL,286,401-407. |
| MLA | Chen, Huaiyin,et al."Electrodeposition of gold nanoparticles on Cu-based metal-organic framework for the electrochemical detection of nitrite".SENSORS AND ACTUATORS B-CHEMICAL 286(2019):401-407. |
入库方式： OAI收割
来源：海洋研究所
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