Carbon nanotubes covalent combined with graphitic carbon nitride for photocatalytic hydrogen peroxide production under visible light
文献类型：期刊论文
| 作者 | Zhao, Xu; Li, Xia; Guo, Tao; Zhao, Shen; Yang, Bo; Xu, Tongguang |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 224页码:725-732 |
| 关键词 | Graphitic carbon nitride Covalent combination Photocatalytic hydrogen peroxide production Oxygen reduction |
| ISSN号 | 0926-3373 |
| 文献子类 | Article |
| 英文摘要 | The carbon nanotubes (CNTs) have been combined with graphitic carbon nitride (g-C3N4) through the amidation reaction. The hybrid catalyst of g-C3N4-CNTs with well-defined and stable structure exhibits efficient catalytic performance (32.6 mu mol h(-1)) for photocatalytic H2O2 production in the presence of formic acid under visible light. The value of electron transfer during the oxygen reduction reaction (ORR) process obtained from the Koutecky-Levich plot for g-C3N4-CNTs (n = 1.96) is higher than that for g-C3N4 (n = 1.29), suggesting that the CNTs covalent combined with g-C3N4 can promote the electrons generation. The p-benzoquinone (PBQ) scavenger experiments, the electron spin resonance (ESR) signal and quantitative experiment of center dot O-2(-) results reveal that the negative shifts of the conduction band (CB) level from g-C3N4 to g-C3N4-CNTs can enhance the single electron reduction of O-2 to center dot O-2(-) and further promote the sequential two-step single-electron O-2 reduction reaction to H2O2. |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/41325]  |
| 专题 | 生态环境研究中心_中国科学院饮用水科学与技术重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhao, Xu,Li, Xia,Guo, Tao,et al. Carbon nanotubes covalent combined with graphitic carbon nitride for photocatalytic hydrogen peroxide production under visible light[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2018,224:725-732. |
| APA | Zhao, Xu,Li, Xia,Guo, Tao,Zhao, Shen,Yang, Bo,&Xu, Tongguang.(2018).Carbon nanotubes covalent combined with graphitic carbon nitride for photocatalytic hydrogen peroxide production under visible light.APPLIED CATALYSIS B-ENVIRONMENTAL,224,725-732. |
| MLA | Zhao, Xu,et al."Carbon nanotubes covalent combined with graphitic carbon nitride for photocatalytic hydrogen peroxide production under visible light".APPLIED CATALYSIS B-ENVIRONMENTAL 224(2018):725-732. |
入库方式： OAI收割
来源：生态环境研究中心
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