中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Rare earth element and yttrium (REY) geochemistry in carbonate reservoirs during deep burial diagenesis: Implications for REY mobility during thermochemical sulfate reduction

文献类型:期刊论文

作者Jiang, Lei1; Cai, Chunfang1; Worden, Richard H.2; Li, Kaikai3; Xiang, Lei (向雷)4; Chu, Xuelei1; Shen, Anjiang5; Li, Wenjun6
刊名CHEMICAL GEOLOGY
出版日期2015-11-15
卷号415页码:87-101
关键词Thermochemical Sulfate Reduction (Tsr) Rare Earth Element And Yttrium (Rey) Carbonate Diagenesis Micro Thermometry Stable Isotope Geochemistry Sr-87/sr-86
ISSN号0009-2541
DOI10.1016/j.chemgeo.2015.09.010
英文摘要

The impact of burial diagenesis (especially deep burial-related processes such as thermochemical sulfate reduction, TSR) on the distribution of rare earth elements and yttrium (REY) in diagenetic minerals in carbonate reservoir has gained little attention even though they may be unique indicators of the diagenetic system being closed or open to external influx of material. Trace element and REY concentrations, Sr-87/Sr-86, delta O-18 and delta C-13 have been determined for limestone, host dolomite, pore-filling calcite (calcite-2), and late stage fracturefilling calcite (calcite-3), barite (barite-2) and anhydrite (anhydrite-3) from Lower Triassic Feixianguan Formation reservoirs in northeast Sichuan Basin, China. Calcite-2, calcite-3, barite-2, and anhydrite-3 precipitated during deep burial (from 110 degrees C to 220 degrees C), demonstrated by petrology and fluid inclusion thermometry. Sr isotope analysis revealed that diagenetic carbonate minerals and anhydrite have largely identical 87Sr/86Sr ratios to Triassic seawater, indicating negligible input of Sr from terrigenous sources and probably a relatively closed diagenetic environment for precipitation of these minerals. Carbon isotope analysis showed that calcite-2 has relatively low delta C-13 values (down to - 18.9% V-PDB), suggesting that they are TSR calcites with the carbonate derived from oxidized, isotopically-light hydrocarbons. Unlike the seawater-like REY patterns of the limestone and dolomites, calcite-3 and anhydrite-3 are enriched in rare earth elements (Sigma REE) and show light rare earth element enrichment and heavy rare earth element depletion, exhibiting a chevron-like pattern of shale normalized REY trends. In contrast, TSR calcite (calcite-2) has similar SREE to the host dolomite but a relatively flat REYSN pattern, suggesting strong variations in elemental and REE compositions of the burial fluids. Significantly, TSR calcite shows a prominent positive Eu anomaly and an unusually high-chondritic Y/Ho ratio. Both yttrium versus holmium fractionation and Eu2+ oxidation to Eu3+ must have occurred during thermochemical sulfate reduction. Hence, a positive Eu anomaly and an elevated Y/Ho ratio may be used as effective proxies to differentiate calcite resulting from TSR from ordinary calcite cement. This is especially useful when carbon isotope analysis cannot be used to give an unambiguous interpretation of the origin of the calcite. (C) 2015 Elsevier B.V. All rights reserved.

WOS关键词Triassic Feixianguan Formation ; Northeast Sichuan Basin ; Mid-atlantic Ridge ; Puguang Gas-field ; Hydrothermal Fluids ; Trace-element ; Ordovician Carbonates ; Stable-isotopes ; Eastern Sichuan ; Central Tarim
资助项目China Natural Science Foundation of China[41125009] ; China Natural Science Foundation of China[41402132] ; China Natural Science Foundation of China[40839906] ; 13th Five-Year National Key Petroleum Project[2016ZX05008003-040] ; International Postdoctoral Exchange Fellowship Program - Office of China Postdoctoral Council (OCPC)[20150035] ; International Postdoctoral Exchange Fellowship Program - Office of China Postdoctoral Council (OCPC)[38]
WOS研究方向Geochemistry & Geophysics
语种英语
WOS记录号WOS:000362454900006
出版者ELSEVIER SCIENCE BV
资助机构China Natural Science Foundation of China ; 13th Five-Year National Key Petroleum Project ; International Postdoctoral Exchange Fellowship Program - Office of China Postdoctoral Council (OCPC)
源URL[http://ir.nigpas.ac.cn/handle/332004/21714]  
专题中国科学院南京地质古生物研究所
通讯作者Cai, Chunfang
作者单位1.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Petr Resources Res, Beijing 100029, Peoples R China
2.Univ Liverpool, Dept Earth Ocean & Ecol Sci, Liverpool L69 3GP, Merseyside, England
3.China Univ Geosci, Energy Resource Dept, Beijing 100083, Peoples R China
4.Nanjing Inst Geol & Palaeontol, State Key Lab Palaeobiol & Stratig, Nanjing 210008, Peoples R China
5.Hangzhou Res Inst Geol, Hangzhou 310023, Zhejiang, Peoples R China
6.Chinese Acad Sci, Inst Geol & Geophys, Key Lab Mineral Resources, Beijing 100029, Peoples R China
推荐引用方式
GB/T 7714
Jiang, Lei,Cai, Chunfang,Worden, Richard H.,et al. Rare earth element and yttrium (REY) geochemistry in carbonate reservoirs during deep burial diagenesis: Implications for REY mobility during thermochemical sulfate reduction[J]. CHEMICAL GEOLOGY,2015,415:87-101.
APA Jiang, Lei.,Cai, Chunfang.,Worden, Richard H..,Li, Kaikai.,Xiang, Lei .,...&Li, Wenjun.(2015).Rare earth element and yttrium (REY) geochemistry in carbonate reservoirs during deep burial diagenesis: Implications for REY mobility during thermochemical sulfate reduction.CHEMICAL GEOLOGY,415,87-101.
MLA Jiang, Lei,et al."Rare earth element and yttrium (REY) geochemistry in carbonate reservoirs during deep burial diagenesis: Implications for REY mobility during thermochemical sulfate reduction".CHEMICAL GEOLOGY 415(2015):87-101.

入库方式: OAI收割

来源:南京地质古生物研究所

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