Selective separation of CO2 using novel mixed matrix membranes based on Pebax and liquid-like nanoparticle organic hybrid materials
文献类型:期刊论文
作者 | Wang, Junfeng1; Fang, Wenjuan1; Luo, Jianquan1; Gao, Ming2,3; Wan, Yinhua1; Zhang, Suojiang2,3; Zhang, Xiangping2,3; Park, Ah-Hyung Alissa2,3 |
刊名 | JOURNAL OF MEMBRANE SCIENCE |
出版日期 | 2019-08-15 |
卷号 | 584页码:79-88 |
ISSN号 | 0376-7388 |
关键词 | Nohm-i-hpe Pebax1657 Mixed Matrix Membrane Co2 Separation |
DOI | 10.1016/j.memsci.2019.04.079 |
英文摘要 | Pebax1657 is known as a promising polymeric membrane material for CO2 separation. In order to further improve its gas separation performance, different polymers containing ethylene oxide (EO) groups are incorporated into the Pebax1657 matrix to form mixed matrix membranes (MMMs). Liquid-like nanoparticle organic hybrid materials (NOHM-I-HPE, "I" stands for "ionic bond" and "HPE" refers to polyetheramine ("PE") with a high ("H") ether group content), which are made of polyetheramine chains tethered onto functionalized silica nanoparticles, have shown high solubility of CO2 . In this study, the homogenous NOHM-I-HPE/Pebax1657 MMMs with different NOHM-I-HPE loadings are prepared and investigated. The results indicate that the addition of NOHM-I-HPE leads to a decrease in glass transition temperature of Pebax1657 and an increase in EO content of the MMMs. Influences of NOHM-I-HPE content on CO2, N-2 and CH4 permeations are investigated at 23 degrees C and 1 bar. For the NOHM-I-HPE loading ranging from 0 to 60 wt%, solubility coefficients of the MMMs for CO2 greatly increase from 1.16 to 3.84 cm(3) (STP)/(cm(3) .bar), while those for CH4 and N-2 only increase from 0.078 to 0.094 cm(3) (STP)/(cm(3).bar) and from 0.013 to 0.026 cm(3) (STP)/(cm(3).bar), respectively. Although the CO2/N-2 selectivity slightly decreases with an increase in the NOHM-I-HPE loading, the CO2/CH4 selectivity is improved in the newly developed NOHM-I-HPE/Pebax1657 MMMs. These results indicate that the NOHM-I-HPE/Pebax1657 MMMs are very promising candidates for selective CO2 separation for various energy related applications. |
WOS关键词 | Gas-transport Properties ; Carbon-dioxide ; Poly(Ethylene Glycol) ; Capture ; Permeation ; Sorption |
资助项目 | Fujian Institute of Innovation, Chinese Academy of Sciences[FJCXY18040101] ; National High Technology Research and Development Program of China (863 Program)[2014AA021006] ; United States National Science Foundation[CBET 1231393] |
WOS研究方向 | Engineering ; Polymer Science |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000468599500007 |
资助机构 | Fujian Institute of Innovation, Chinese Academy of Sciences ; National High Technology Research and Development Program of China (863 Program) ; United States National Science Foundation |
源URL | [http://ir.ipe.ac.cn/handle/122111/28123] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Wan, Yinhua; Park, Ah-Hyung Alissa |
作者单位 | 1.Chinese Acad Sci, Univ Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100190, Peoples R China 2.Columbia Univ, Dept Earth & Environm Engn, Lenfest Ctr Sustainable Energy, 500 W 120th St, New York, NY 10027 USA 3.Columbia Univ, Dept Chem Engn, Lenfest Ctr Sustainable Energy, 500 W 120th St, New York, NY 10027 USA |
推荐引用方式 GB/T 7714 | Wang, Junfeng,Fang, Wenjuan,Luo, Jianquan,et al. Selective separation of CO2 using novel mixed matrix membranes based on Pebax and liquid-like nanoparticle organic hybrid materials[J]. JOURNAL OF MEMBRANE SCIENCE,2019,584:79-88. |
APA | Wang, Junfeng.,Fang, Wenjuan.,Luo, Jianquan.,Gao, Ming.,Wan, Yinhua.,...&Park, Ah-Hyung Alissa.(2019).Selective separation of CO2 using novel mixed matrix membranes based on Pebax and liquid-like nanoparticle organic hybrid materials.JOURNAL OF MEMBRANE SCIENCE,584,79-88. |
MLA | Wang, Junfeng,et al."Selective separation of CO2 using novel mixed matrix membranes based on Pebax and liquid-like nanoparticle organic hybrid materials".JOURNAL OF MEMBRANE SCIENCE 584(2019):79-88. |
入库方式: OAI收割
来源:过程工程研究所
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