Inhibiting degradation of cellulose dissolved in ionic liquids via amino acids
文献类型：期刊论文
| 作者 | Yang, Jiming1,2; Lu, Xingmei1,2; Yao, Xiaoqian1; Li, Yao1; Yang, Yongqing1,2; Zhou, Qing1,2; Zhang, Suojiang1,2 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2019-05-21 |
| 卷号 | 21期号:10页码:2777-2787 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c9gc00334g |
| 英文摘要 | Although ionic liquids (ILs) are efficient solvents for dissolving cellulose, long time dissolution (for example 24 h) could lead to cellulose degradation, especially at high temperatures (for example 130 degrees C), limiting the use of ILs in the cellulose industry. On the premise of sufficient dissolution, inhibiting cellulose degradation in 1-butyl-3-methylimidazolium chloride [C(4)mim]Cl, 1-ethyl-3-methylimidazolium chloride [C(2)mim]Cl and 1-allyl-3-methylimidazolium chloride [Amim]Cl at 130 degrees C was achieved by the addition of amino acids. The results show that the cellulose regeneration rate increased from 0.00% to 90.02% at 130 degrees C for 24 h when 1.25 wt% of l-arginine was added to [C(4)mim]Cl. It is concluded that l-arginine can form an intermolecular hydrogen bond with one of the three ipsilateral hydroxyls of cellulose, which prevents the cation [C(4)mim](+) or anion Cl- from simultaneously forming three hydrogen bonds with the three ipsilateral hydroxyls of cellulose, successfully inhibiting cellulose degradation. This work expands the application of ILs in the cellulose industry. |
| WOS关键词 | STEAM EXPLOSION ; FORCE-FIELD ; DISSOLUTION ; LIGNOCELLULOSE ; FIBERS ; POLYMERIZATION ; PRETREATMENT ; BEHAVIOR ; WOOD |
| 资助项目 | National Basic Research Program of China[2015CB251401] ; National Natural Scientific Foundation of China[21878292] ; National Natural Scientific Foundation of China[21776289] ; K. C. Wong Education Foundation ; Strategic Priority Research Program of Chinese Academy of Science[XDA21060300] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000468627800022 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Basic Research Program of China ; National Natural Scientific Foundation of China ; K. C. Wong Education Foundation ; Strategic Priority Research Program of Chinese Academy of Science |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28191]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Lu, Xingmei; Zhang, Suojiang |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beying Key Lab Ion Liquids Clean Proc,CAS Key Lab, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Jiming,Lu, Xingmei,Yao, Xiaoqian,et al. Inhibiting degradation of cellulose dissolved in ionic liquids via amino acids[J]. GREEN CHEMISTRY,2019,21(10):2777-2787. |
| APA | Yang, Jiming.,Lu, Xingmei.,Yao, Xiaoqian.,Li, Yao.,Yang, Yongqing.,...&Zhang, Suojiang.(2019).Inhibiting degradation of cellulose dissolved in ionic liquids via amino acids.GREEN CHEMISTRY,21(10),2777-2787. |
| MLA | Yang, Jiming,et al."Inhibiting degradation of cellulose dissolved in ionic liquids via amino acids".GREEN CHEMISTRY 21.10(2019):2777-2787. |
入库方式： OAI收割
来源：过程工程研究所
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