Polyketone-based membrane support improves the organic solvent resistance of laccase catalysis
文献类型：期刊论文
| 作者 | Liu, Cuijing1; Saeki, Daisuke2; Cheng, Liang1; Luo, Jianquan3; Matsuyama, Hideto1 |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2019-05-15 |
| 卷号 | 544页码:230-240 |
| 关键词 | Enzymatic membrane reactors Enzyme immobilization Polyketone Lactase Organic solvent |
| ISSN号 | 0021-9797 |
| DOI | 10.1016/j.jcis.2019.03.003 |
| 英文摘要 | Enzymes play vital roles in biological transformations due to incomparable selectivity. Enzymatic membrane reactors (EMRs) combine enzymes with membranes, and many researchers have studied the synergistic effect of EMRs exerting on enzyme performance. Before the utility of EMRs can expand from natural aqueous media to organic solvents, robust membranes must be developed to promote enzyme protection from hostile forms of media. For this study, laccase was immobilized on an organic-solvent resistant hydroxylated polyketone (PK-OH) membrane via covalent bonds and served as a model enzyme. Ketone groups facilitated the immobilization via hydrogen bonds, leading to a high immobilization density of 462 mu g/cm(2). In homogeneous aqueous-organic solvents, the activity of immobilized laccase was up to 3.5 times greater than that of free laccase towards 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid). In addition, the results also showed improved activity towards highly concentrated 2,4,6-trichlorophenol and bisphenol A (1.4 g/L). Furthermore, the activity in filtration mode showed a 240% increase over that in batch mode. The immobilized laccase maintained its activity after 40 days of storage, 10 reuse cycles, and 50 h of continuous reaction. These results show that robust polyketone based membrane support will create opportunities for the application of EMRs in aqueous-organic solvents. (C) 2019 Elsevier Inc. All rights reserved. |
| WOS关键词 | MICROFILTRATION MEMBRANE ; NANOFIBROUS MEMBRANE ; IMMOBILIZED LACCASE ; BISPHENOL-A ; ENZYMES ; REACTOR ; DEGRADATION ; STRATEGIES ; SEPARATION ; DOPAMINE |
| 资助项目 | Special Coordination Funds for Promoting Science and Technology, Creation of Innovation Centers for Advanced Interdisciplinary Research Areas (Innovative Bioproduction, Kobe) from the Ministry of Education, Culture, Sports, Science and Technology, Japan ; China Scholarship Council (CSC) |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000463310100024 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | Special Coordination Funds for Promoting Science and Technology, Creation of Innovation Centers for Advanced Interdisciplinary Research Areas (Innovative Bioproduction, Kobe) from the Ministry of Education, Culture, Sports, Science and Technology, Japan ; China Scholarship Council (CSC) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28200]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Saeki, Daisuke; Matsuyama, Hideto |
| 作者单位 | 1.Kobe Univ, Ctr Membrane & Film Technol, Dept Chem Sci & Engn, Nada Ku, 1-1 Rokkodai, Kobe, Hyogo 6578501, Japan 2.Shinshu Univ, Dept Chem Mat, Fac Engn, 4-17-1 Wakasato, Nagano 3808553, Japan 3.Univ Chinese Acad Sci, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Cuijing,Saeki, Daisuke,Cheng, Liang,et al. Polyketone-based membrane support improves the organic solvent resistance of laccase catalysis[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2019,544:230-240. |
| APA | Liu, Cuijing,Saeki, Daisuke,Cheng, Liang,Luo, Jianquan,&Matsuyama, Hideto.(2019).Polyketone-based membrane support improves the organic solvent resistance of laccase catalysis.JOURNAL OF COLLOID AND INTERFACE SCIENCE,544,230-240. |
| MLA | Liu, Cuijing,et al."Polyketone-based membrane support improves the organic solvent resistance of laccase catalysis".JOURNAL OF COLLOID AND INTERFACE SCIENCE 544(2019):230-240. |
入库方式： OAI收割
来源：过程工程研究所
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