Biodiesel production using calcium-based catalyst from venus shell: Modeling of startup production in an industrial reactor
文献类型：期刊论文
| 作者 | Sun, Y; Zhang, JP; Sun, Z; Zhang, L; Sun, Yong; Zhang, Jingping; Sun, Zhi; Zhang, Lian |
| 刊名 | ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY
 |
| 出版日期 | 2019 |
| 卷号 | 38期号:3 |
| 关键词 | biodiesel FREE FATTY-ACIDS industrial production ACTIVATED CARBON process safety SOYBEAN OIL catalyst TRANSESTERIFICATION PERFORMANCE WASTE CAO OPTIMIZATION SIMULATION REMOVAL |
| ISSN号 | 1944-7442 |
| DOI | 10.1002/ep.13053 |
| 文献子类 | Article |
| 英文摘要 | Calcium oxide-based catalyst was produced from Venus shell by fast fluidized bed calcination for biodiesel synthesis. The kinetics of biodiesel synthesis was found to be a pseudo-first-order reaction at the experimental conditions. The obtained kinetic parameters were used for modeling the startup operation of biodiesel production in an industrial continuous stirred tank reactor (CSTR). The model was found to agree well with the reagent concentration and temperature profiles in a real production practice during biodiesel production. The variations of initial temperature, initial reagent concentration in the reactor was investigated. It was found that the reagent concentration and temperature oscillated around the final steady state. From safety operation perspective, the first 4 h were found to be the most unsteady period during continuous production. The initial concentration of waste fry oil (WFO) was also found to be critical to the safe operation of CSTR. A violation of the settings for safe operation of CSTR will be triggered once the initial concentration of WFO in CSTR reaches 500 mol m(-3). (c) 2018 American Institute of Chemical Engineers Environ Prog, 38:e13053, 2019 |
| WOS记录号 | WOS:000469045900027 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28212]  |
| 专题 | 中国科学院过程工程研究所 |
| 推荐引用方式 GB/T 7714 | Sun, Y,Zhang, JP,Sun, Z,et al. Biodiesel production using calcium-based catalyst from venus shell: Modeling of startup production in an industrial reactor[J]. ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY,2019,38(3). |
| APA | Sun, Y.,Zhang, JP.,Sun, Z.,Zhang, L.,Sun, Yong.,...&Zhang, Lian.(2019).Biodiesel production using calcium-based catalyst from venus shell: Modeling of startup production in an industrial reactor.ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY,38(3). |
| MLA | Sun, Y,et al."Biodiesel production using calcium-based catalyst from venus shell: Modeling of startup production in an industrial reactor".ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY 38.3(2019). |
入库方式： OAI收割
来源：过程工程研究所
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