Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base
文献类型：期刊论文
| 作者 | Lin, Yang1; Zhu, De-Ping2,3; Du, Yi-Ran2,3; Zhang, Rui1; Zhang, Suo-Jiang2,3; Xu, Bao-Hua2,3 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2019-04-19 |
| 卷号 | 21期号:8页码:2693-2698 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.9b00679 |
| 英文摘要 | The combination of tris(pyrazolyl)borate cobalt complexes and Lewis base is developed as an efficient catalyst precursor in the homogeneous hydrogenation. A broad substrate scope including carbonyls, alkenes, enamines, and imines is reduced with 60 atm of H-2 at 60 degrees C. Mechanistic studies support the hydrogenation operates through a frustrated Lewis pair (FLP)-like reduction process. These results highlight the development of novel non-noble metal catalytic processes, when combined with the diverse small molecule activation chemistry associated with FLPs. |
| WOS关键词 | ASYMMETRIC HYDROGENATION ; SELECTIVE HYDROGENATION ; CARBENE INSERTION ; PINCER COMPLEXES ; CARBON-DIOXIDE ; IRON ; ACTIVATION ; LIGAND ; POLY(PYRAZOLYL)BORATE ; DEHYDROGENATION |
| 资助项目 | National Natural Science Foundation of China[U1662133] ; National Natural Science Foundation of China[21374029] ; K. C. Wong Education Foundation[GJTD-2018-04] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000465644300043 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; K. C. Wong Education Foundation |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28234]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhang, Rui; Xu, Bao-Hua |
| 作者单位 | 1.East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Yang,Zhu, De-Ping,Du, Yi-Ran,et al. Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base[J]. ORGANIC LETTERS,2019,21(8):2693-2698. |
| APA | Lin, Yang,Zhu, De-Ping,Du, Yi-Ran,Zhang, Rui,Zhang, Suo-Jiang,&Xu, Bao-Hua.(2019).Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base.ORGANIC LETTERS,21(8),2693-2698. |
| MLA | Lin, Yang,et al."Tris(pyrazolyl)borate Cobalt-Catalyzed Hydrogenation of C = O, C = C, and C = N Bonds: An Assistant Role of a Lewis Base".ORGANIC LETTERS 21.8(2019):2693-2698. |
入库方式： OAI收割
来源：过程工程研究所
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